液相氧化剂氧化法制备六氟环氧丙烷的研究进展  

Research Progress on the Preparation of Hexafluoropropylene Oxide by Oxidation of Liquid Phase Oxidant

作　　者：吴双根 吴志刚[2] 林金元 吴宇鹏[2] 江泳[2] 王训遒[1] WU Shuanggen;WU Zhigang;LIN Jinyuan;WU Yupeng;JIANG Yong;WANG Xunqiu(School of Chemical Engineering,Zhengzhou University,Zhengzhou 450001,China;Zhejiang Juhua Co.,Ltd.,Electrochemistry Plant,Quzhou 324004,China)

机构地区：[1]郑州大学化工学院,河南郑州450001 [2]浙江巨化股份有限公司电化厂,浙江衢州324004

出　　处：《有机氟工业》2023年第4期31-34,共4页Organo-Fluorine Industry

摘　　要：简要介绍了六氟环氧丙烷的物化性质、应用及合成工艺,重点介绍了过氧化氢氧化法和次氯酸钠氧化法氧化六氟丙烯制备六氟环氧丙烷的工艺研究。相比于其他六氟环氧丙烷的制备方法,液相氧化剂氧化法具有反应条件温和、反应速率大、产物选择性高且不存在氧爆风险等优势,一直以来备受人们关注。The physical and chemical properties,application and synthesis method of hexafluoropropylene oxide were briefly introduced in this paper.The preparation process of hexafluoropropylene oxide by hydrogen peroxide oxidation and sodium hypochlorite oxidation of hexafluoropropylene was also introduced.Compared with other preparation methods of hexafluoropropylene oxide,the liquid phase oxidant oxidation method has many advantages,such as mild reaction conditions,fast reaction rate,high product selectivity and no risk of oxygen explosion.Therefore,this method has been attracting the attention of researchers.

关 键 词：六氟环氧丙烷 液相氧化剂氧化法 过氧化氢氧化法 次氯酸钠氧化法 

分 类 号：TQ223.26[化学工程—有机化工]