金属配合物的机械发光:进展与应用  

Mechanoluminescence of metal complexes:Progress and applications

作　　者：王海兰 魏小雨 王娟 孙浩东 黄荣娟 UBBA Eethamukkala 于涛 WANG Hai-lan;WEI Xiao-yu;WANG Juan;SUN Hao-dong;HUANG Rong-juan;UBBA Eethamukkala;YU Tao(Frontiers Science Center for Flexible Electronics(FSCFE),Shaanxi Institute of Flexible Electronics(SIFE)and Ningbo Institute of NPU(NINPU),Northwestern Polytechnical University,Xi’an 710072,China;OMC Research Laboratory,Department of Chemistry,School of Advanced Sciences,VIT Vellore,Tamilnadu,India)

机构地区：[1]Frontiers Science Center for Flexible Electronics(FSCFE),Shaanxi Institute of Flexible Electronics(SIFE)and Ningbo Institute of NPU(NINPU),Northwestern Polytechnical University,Xi’an 710072,China [2]OMC Research Laboratory,Department of Chemistry,School of Advanced Sciences,VIT Vellore,Tamilnadu,India

出　　处：《Journal of Central South University》2023年第12期3897-3923,共27页中南大学学报（英文版）

基　　金：Projects(51703253,52103230,62275217)supported by the National Natural Science Foundation of China;Project supported by the Fundamental Research Funds for the Central Universities,China;Project(2020GXLH-Z-010)supported by the Key Research and Development Program of Shaanxi Province,China;Project(cstc2020jcyjmsxmX0931)supported by Chongqing Science and Technology Fund,China;Projects(2020A1515110603,2021A1515010633)supported by Guangdong Basic and Applied Basic Research Foundation,China;Projects(202003N4059,202003N4060)supported by Ningbo Natural Science Foundation,China;Project(2020Z073053007)supported by Aerospace Science Foundation of China。

摘　　要：摩擦发光(ML)是由机械力作用在材料上引起的发光现象。近年来,金属配合物ML材料因其独特的光学发射特性而受到广泛关注,在应力传感、防伪、结构健康监测、医疗健康、结构检测等领域有着广阔的应用前景。本文综述了近年来具有摩擦发光性质的金属配合物材料的研究进展,包括镧系金属配合物和过渡金属配合物。此外,还讨论了摩擦发光的产生机制、设计原理、光物理性质及其应用前景。本综述将为构建金属配合物摩擦发光材料以及拓展其在应力传感、结构检测等方面的应用提供启发和指导。Mechanoluminescence(ML)is a light emission phenomenon caused by mechanical force on a substance.Recently,metal complexes mechanoluminescence materials are attracting widespread attention owing to their distinctive optical emission properties,which create exciting opportunities in various fields,such as stress sensing,anticounterfeiting,structural health monitoring,medical health monitoring,structure detection and other fields.In this review,we summarized the recent progress of metal complex mechanoluminescence materials,including lanthanide metal complexes and transition metal complexes.In addition,the underlying mechanoluminescence mechanisms,design principles of mechanoluminescence,detailed photophysical behaviors,and their potential applications have been discussed.This review will provide inspiration and guidelines for constructing metal complexes mechanoluminescence materials and expanding their potential applications in stress sensing,structure detection and so on.

关 键 词：摩擦发光 金属配合物 压电性能 非中心对称 结构检测 

分 类 号：O641.4[理学—物理化学]