过渡金属化合物催化剂在电解水析氢中的应用进展  

Application progress of transition metal compound catalysts in hydrogen evolution of electrolyzed water

作　　者：范少星 安立宝 张志明 FAN Shao-xing;AN Li-bao;ZHANG Zhi-ming(School of Mechanical Engineering,North China University of Technology,Tangshan 063210,China;School of Materials Science and Engineering,North China University of Technology,Tangshan 063210,China)

机构地区：[1]华北理工大学机械工程学院,河北唐山063210 [2]华北理工大学材料科学与工程学院,河北唐山063210

出　　处：《应用化工》2023年第12期3371-3375,共5页Applied Chemical Industry

基　　金：国家自然科学基金项目(51472074)。

摘　　要：概述了过渡金属氧化物、硫化物、磷化物以及其复合材料作为电解水析氢反应催化剂的应用进展。讨论了过渡金属化合物中纳米结构、杂原子掺杂和缺陷工程等不同改性方法对电解水析氢反应的影响,分析了过渡金属化合物复合材料在电解水析氢反应中具有高效率的原因。总结了过渡金属化合物催化剂在电解水析氢领域应用面临的挑战和未来的机遇。This paper mainly summarizes the application progress of transition metal oxides,sulfides,phosphides and their composites as catalysts for hydrogen evolution reaction in electrolytic water.The effects of different modification methods such as nanostructure,heteroatom doping and defect engineering in transition metal compounds on the hydrogen evolution reaction of electrolytic water were discussed.The reasons for the high efficiency of transition metal compound composites in the hydrogen evolution reaction of electrolytic water were also analyzed.Finally,the challenges and future opportunities of the application of transition metal compound catalysts in the field of electrolytic water hydrogen evolution are summarized.

关 键 词：过渡金属化合物 催化剂 电解水 析氢反应 复合材料 应用进展 

分 类 号：TQ116.2[化学工程—无机化工] TQ426