NiMo基非晶合金电催化析氢反应的进展  

Recent progress in NiMo-based amorphous alloys for electrocatalytic hydrogen evolution reaction

作　　者：张思璇 黄金昭[1] 丁殿金 汤军 邓小龙 Si-xuan ZHANG;Jin-zhao HUANG;Dian-jin DING;Jun TANG;Xiao-long DENG(School of Physics and Technology,University of Jinan,Jinan 250022,China;School of Mathematics and Physics,Anhui University of Technology,Ma’anshan 243032,China)

机构地区：[1]济南大学物理科学与技术学院,济南250022 [2]安徽工业大学数学与物理学院,马鞍山243032

出　　处：《Transactions of Nonferrous Metals Society of China》2024年第1期26-49,共24页中国有色金属学报（英文版）

基　　金：supported by the Introduction and Cultivation Plan of Young Innovative Talents in Colleges and Universities of Shandong Province, China;the Natural Science Foundation of Shandong Province, China (No. ZR2020ME052);the Natural Science Research Fund for Colleges and Universities in Anhui Province, China (No. KJ2021A0387);Independent Cultivation Program of Innovation Team of Jinan City, China (No. 2019GXRC011)。

摘　　要：电催化水分解产生绿色氢气是发展可持续能源体系的重要途径之一。由过渡金属Ni、Mo组成的具有高活性、低成本的非晶态合金被广泛认为是一种有效的制氢催化剂。重点关注以镍钼(NiMo)基非晶合金为代表的催化剂,总结非晶态合金的制备方法及其在催化领域的应用,分别叙述NiMo合金、NiMo基中熵合金和NiMo基高熵合金在电催化析氢反应(HER)中的应用。结果表明,在合理的功能导向设计下,通过对关键科学及技术问题的解决,NiMo基非晶态合金催化剂能够表现出良好的析氢性能,最后提出在制备技术、组分调控、纳米化、电子结构以及活化机理5个方面还有待解决的问题。这对于催化剂的设计、制备、构效关系及催化机理的研究具有一定的参考价值。Electrocatalytic water splitting to produce green hydrogen is one of the important ways to develop sustainable energy systems.Highly active,low-cost amorphous alloys composed of transition metals Ni and Mo are widely regarded as efficient catalysts for hydrogen production.The catalysts represented by nickel-molybdenum(NiMo)-based amorphous alloys are focused on,the synthesis methods of amorphous alloys and their applications in the field of catalysis are summarized,and the application of NiMo alloys,NiMo-based medium entropy alloys,and NiMo-based high-entropy alloys are described respectively in electrocatalytic hydrogen evolution reaction(HER).In a word,NiMo-based amorphous alloy catalysts exhibit excellent hydrogen evolution performance by solving key scientific and technical problems with a reasonable function-oriented design.Finally,five issues in terms of preparation technology,component regulation,nanoscale,electronic structure and catalytic mechanism are proposed.This gives a clue for the design,preparation,structure-activity relationship and catalytic mechanism of catalysts.

关 键 词：NiMo合金 非晶合金 水电解 析氢反应 

分 类 号：TG139.8[一般工业技术—材料科学与工程] TQ116.21[金属学及工艺—合金] TQ426.8[金属学及工艺—金属学]