MOFs基环己烷选择性氧化催化剂研究进展  

Research progress on MOFs-based catalysts for selective oxidation of cyclohexane

作　　者：叶涵 张英 陈建兵 YE Han;ZHANG Ying;CHEN Jian-bing(SINOPEC Dalian Research Institute of Petroleum and Petrochemicals Co.,Ltd.,Dalian 116041,China)

机构地区：[1]中石化(大连)石油化工研究院有限公司,辽宁大连116041

出　　处：《现代化工》2024年第2期81-85,共5页Modern Chemical Industry

基　　金：中国石油化工股份有限公司合同项目(112212)。

摘　　要：系统综述了MOFs基材料作为多相催化剂、载体和前驱体在环己烷选择性催化氧化方面的研究进展,包括本征MOFs、MOFs复合物和MOFs衍生物。重点介绍了MOFs基材料中活性位点类型、组成及比例和孔结构、孔环境等对环己烷催化氧化过程转化率、选择性的影响效果,指出了MOFs基材料面临的挑战并展望了其未来发展方向。A systematic review is presented about the latest research progress in the utilization of MOFs-based materials as heterogeneous catalysts,supports,and precursors for selective catalytic oxidation of cyclohexane.It involves intrinsic MOFs,MOF composites,and MOF derivatives.This review emphasizes the influences of active site type,composition,and ratio,as well as the structure and environment of pores,on the conversion rate and selectivity of cyclohexane catalytic oxidation over MOFs-based materials.Additionally,the challenges faced by MOFs-based materials are identified,and their prospects for the future are proposed.

关 键 词：MOFS 环己烷 催化氧化 多相催化 金属位点 

分 类 号：TQ234.21[化学工程—有机化工] TQ233.1TQ426