发光稀土-硫杂杯[4]芳烃配合物的研究进展  

Recent Advances of Luminescent Lanthanide‐Thiacalix[4]arene Complexes

作　　者：李子萍 毕研峰 LI Ziping;BI Yanfeng(School of Petrochemical Engineering,Liaoning Petrochemical University,Fushun Liaoning 113001,China)

机构地区：[1]辽宁石油化工大学石油化工学院,辽宁抚顺113001

出　　处：《辽宁石油化工大学学报》2024年第1期1-8,共8页Journal of Liaoning Petrochemical University

基　　金：国家自然科学基金项目(91961110)。

摘　　要：硫杂杯芳烃作为配体具有识别能力强、可“衍生化”、稳定性较好等优点。稀土离子与硫杂杯[4]芳烃配体易形成多功能金属簇配合物。稀土-硫杂杯[4]芳烃因具有独特的催化、磁学和光学等性质而受到越来越多的关注。硫杂杯[4]芳烃与稀土离子可通过酚羟基和桥连硫的配位发生有效的“天线效应”,使稀土离子敏化发光。综述了有关稀土-硫杂杯[4]芳烃配合物在光学性质方面的研究现状,论述了其结构、光学性质及应用。Thiacalix[4]arene ligands have the advantages of high recognition,derivatization,excellent stability and other advantages.Lanthanide(Ln)ions can coordinate with thiacalix[4]arene ligands to form multi-functional coordination clusters,which received increasing attention due to their unique catalytic,magnetic,optical properties.Thiacalix[4]arene can sensitize Ln ions to luminescence by the coordination of phenol and S groups via the"Antenna effect".This paper reviewed recent advances in structures,luminescent properties,and applications of luminescent Ln-thiacalix[4]arene complexes.

关 键 词：硫杂杯[4]芳烃 稀土离子 配位簇 发光性质 

分 类 号：TQ139.2[化学工程—无机化工]