MOF衍生碳基材料的电催化应用及其先进表征技术  

MOF-derived nanocarbon materials for electrochemical catalysis and their advanced characterization

作　　者：陈曦[1] 李明轩[1] 闫金伦 张龙力[1,2] CHEN Xi;LI Ming-xuan;Yan Jin-lun;Zhang Long-li(College of Chemistry and Chemical Engineering,China University of Petroleum(East China),Qingdao 266580,China;State Key Laboratory of Heavy Oil Processing,China University of Petroleum(East China),Qingdao 266580,China)

机构地区：[1]中国石油大学(华东)化学化工学院,山东青岛266580 [2]中国石油大学(华东)重质油国家重点实验室,山东青岛266580

出　　处：《新型炭材料（中英文）》2024年第1期78-99,共22页New Carbon Materials

基　　金：中国石油大学(华东)自主创新科研计划项目(23CX06009A).

摘　　要：鉴于对清洁和可持续能源的需求,来自金属有机框架(MOFs)的纳米炭衍生物正崭露头角,成为电催化能量转化的独特催化剂。这些MOF衍生的纳米炭材料不仅保持了MOFs组成可定制和结构多样性等优势,而且在热解过程中可有效防止金属纳米颗粒和金属氧化物的聚集。因此,它们提高了电催化效率,改善了电导率,并在燃料电池和金属-空气电池等绿色能源技术中发挥了关键作用。该综述以MOF衍生碳基材料的炭化机制为起点,随后深入探讨了固有炭缺陷、金属和非金属原子掺杂,并研究了这些材料的合成策略。此外,全面介绍了先进的表征技术,包括原位映射和原位光谱学。最后,对MOF衍生碳基材料作为电催化剂的研究前景提供了见解。该综述的主要目标是为当前MOF衍生碳基电催化剂的状况提供更清晰的视角,鼓励更高效电催化材料的发展。Because of the demand for clean and sustainable energy sources,nanocarbons,modified carbons and their composite materials derived from metal-organic frameworks(MOFs)are emerging as distinct catalysts for electrocatalytic energy conversion.These materials not only inherit the advantages of MOFs,like customizable dopants and structural diversity,but also effectively pre-vent the aggregation of nanoparticles of metals and metal oxides during pyrolysis.Consequently,they increase the electrocatalytic ef-ficiency,improve electrical conductivity,and may play a pivotal role in green energy technologies such as fuel cells and metal-air batteries.This review first explores the carbonization mechanism of the MOF-derived carbon-based materials,and then considers 3 key aspects:intrinsic carbon defects,metal and non-metal atom doping,and the synthesis strategies for these materials.We also provide a comprehensive introduction to advanced characterization techniques to better understand the basic electrochemical catalys-is processes,including mapping techniques for detecting localized active sites on electrocatalyst surfaces at the micro-to nano-scale and in-situ spectroscopy.Finally,we offer insights into future research concerning their use as electrocatalysts.Our primary object-ive is to provide a clearer perspective on the current status of MOF-derived carbon-based electrocatalysts and encourage the develop-ment of more efficient materials.

关 键 词：金属-有机框架材料 纳米炭材料 电催化 先进表征方法 

分 类 号：O643.36[理学—物理化学]