负载型烯烃氢甲酰化催化剂研究进展  

Research progress of supported catalysts for hydroformylation of olefins to aldehyde

作　　者：马萍 和树立 陈述卫 马好文 谢元 孙利民 MA Ping;HE Shu-li;CHEN Shu-wei;MA Hao-wen;XIE Yuan;SUN Li-min(Lanzhou Petrochemical Research Center,Petrochemical Research Institute,PetroChina,Lanzhou 730060,China;Ministry of Science and Technology Development,Guangdong Petrochemical Company,PetroChina,Jieyang 522000,China;Refining Production Department II,Guangdong Petrochemical Company,PetroChina,Jieyang 522000,China)

机构地区：[1]中国石油石油化工研究院兰州化工研究中心,甘肃兰州730060 [2]中国石油广东石化公司科技发展部,广东揭阳5220003 [3]中国石油广东石化公司炼油生产二部,广东揭阳5220003

出　　处：《石化技术与应用》2024年第1期75-80,共6页Petrochemical Technology & Application

基　　金：中国石油石油化工研究院资助项目(项目编号:21-CB-09-01)。

摘　　要：对负载型配合物催化剂、负载型纳米粒子催化剂以及负载型单原子催化剂的研究进展及其在烯烃氢甲酰化制醛反应中的应用进行了综述,对通过调变载体性质、助剂种类、活性组分粒径等方式改善负载型催化剂的性能进行了分析,并对烯烃氢甲酰化催化剂的研究方向进行了展望。指出降低催化剂中金属Rh的含量,提高负载型催化剂的性能,并将它们应用到工业生产中,是当下和未来的努力方向。The research progress of supported complex catalysts,supported nanoparticle catalysts,and supported single-atom catalysts and their applications in the hydroformylation of olefins to aldehydes were reviewed,the improvement of the performance of supported catalysts by modifying the characteristic of the support,the type of the additive,and the particle size of the active component were analyzed,and the research direction of the catalysts for hydroformylation of olefins were also prospected.It was pointed out that reducing the content of Rh in catalysts and improving the performance of supported catalysts and applying them to industrial production were the present and future direction.

关 键 词：烯烃 氢甲酰化 负载型催化剂 配合物 纳米粒子 单原子 

分 类 号：TQ215[化学工程—有机化工]