热驱动CO_(2)多相催化合成化学品研究进展  

Research progress on thermal catalytic conversion of carbon dioxide

作　　者：姜瑞君 李玉涛 王振峰[1] 王玉清 郭小惠 丁健[1,2] JIANG Ruijun;LI Yutao;WANG Zhenfeng;WANG Yuqing;GUO Xiaohui;DING Jian(Laboratory of Carbon Capture and Efficient Utilization,School of Chemistry and Chemical Engineering,Inner Mongolia University of Science&Technology,Baotou 014010,Inner Mongolia,China;Inner Mongolia Key Laboratory of Coal Chemical Engineering&Comprehensive Utilization,Inner Mongolia University of Science&Technology,Baotou 014010,Inner Mongolia,China)

机构地区：[1]内蒙古科技大学化学与化工学院碳捕集与高效利用实验室,内蒙古包头014010 [2]内蒙古科技大学内蒙古自治区煤化工与煤炭综合利用重点实验室,内蒙古包头014010

出　　处：《精细化工》2024年第2期302-314,400,共14页Fine Chemicals

基　　金：国家自然科学基金项目(22062018);内蒙古自治区高等学校青年科技英才支持计划项目(NJYT22070);内蒙古自治区高等学校科学研究项目(NJZZ23063)。

摘　　要：CO_(2)分子较高的化学惰性导致其选择性活化及可控转化极具挑战。相对于电和光驱动CO_(2)催化转化反应,热驱动CO_(2)多相催化转化反应具有操作简便、目标产物可调且产品收率较高等优势。通过该类反应实现CO_(2)还原或非还原制备多种化学品,既可促进CO_(2)的资源化利用,又可有效缓解温室效应,在环保、能源和材料等领域具有重要意义。该文对热驱动多相催化CO_(2)转化为CO、CH_(4)、甲酸、甲醇、碳氢化合物和其他精细化学品的研究现状进行了综合评述,重点讨论了反应机理、所用催化剂及反应体系的研究进展,并对其未来的研究方向进行了前景展望和探讨。Due to the high chemical inertness of CO_(2) molecules,selective activation and controllable conversion of CO_(2) become extremely challenging.Compared with electric-or photo-driven catalytic conversion,thermal-driven heterogeneous catalytic conversion of CO_(2) is a simple method with adjustable target products and high product yield.Most importantly,the value-added products obtained from the reduction or non-reduction of CO_(2) can effectively promote the utilization of CO_(2) and alleviate the greenhouse effect,which is of great significance in the fields of environmental protection,energy,and materials.In this review,the development status quo on the thermal-driven heterogeneous catalytic conversion of CO_(2) for the synthesis of CO,CH_(4),formic acid,methanol,hydrocarbons,and other fine chemicals were reviewed,with the emphasis on the research progresses on reaction mechanism,catalysts and reaction process.Moreover,the existing problems and the future development directions were discussed.

关 键 词：CO_(2) 热驱动多相催化剂 反应体系 高附加值产物 

分 类 号：X701[环境科学与工程—环境工程] O643.36[理学—物理化学]