Bioabsorbable fabrication of molybdenum nitride/carbon nanocomposites for supercapacitors and metal ion batteries with robust stability  

作　　者：Qiang-Hong Wu Huan-Zhong Zeng You-Zhi Wu Fen Ran 

机构地区：[1]State Key Laboratory of Advanced Processing and Recycling of Non-Ferrous Metals,School of Materials Science and Engineering,Lanzhou University of Technology,Lanzhou 730050,China

出　　处：《Rare Metals》2023年第12期4212-4225,共14页稀有金属（英文版）

基　　金：financially supported by the National Natural Science Foundation of China (Nos.51763014 and52073133);the Key Talent Project Foundation of Gansu Province;Joint Fund between Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals (No.18LHPY002);the Program for Hongliu Distinguished Young Scholars in Lanzhou University of Technology。

摘　　要：Metal nitride is one of the best anode materials of the energy storage device;however,the low stability of the pure metal nitride limits its wide applications.In this work,a new method of bioabsorbable fabrication was developed for preparing molybdenum nitride that corporates into the porous carbon materials.The molybdenum ions in pollutions could be easily absorbed by Ligustrum quihoui,and the transportation,accumulation,and circulation of molybdenum ions in Ligustrum quihoui were studied.The obtained composite material of biochar and molybdenum nitride is employed as anode material of supercapacitors and batteries which exhibits good electrochemical performance,especially the rate and long lifespan aspects.Typically,it is found that the specific capacity is344 F·g^(-1)at current density of 0.5 A·g^(-1)in 2 mol·L^(-1)KOH,and the capacitance retention and coulomb efficiency are above 90%after 10,000 cycles.It should be noted that the novel approach combines fabricating anode materials with advanced nanostructure and suppressing the environmental problems with metal pollution at the same time.

关 键 词：Metal pollution Ligustrum quihoui SUPERCAPACITORS Metal ions batteries Anode materials 

分 类 号：TM53[电气工程—电器] TM912[一般工业技术—材料科学与工程] TB33