Recent progress on copper catalysts with different surface states for CO_(2)electroreduction  

作　　者：Wenjun Zhang Yang Yang Donggang Guo Lu Liu 

机构地区：[1]Tianjin Key Laboratory of Environmental Remediation and Pollution Control,College of Environmental Science and Engineering,Nankai University,Tianjin 300350,China [2]Shanxi Laboratory for Yellow River,College of Environment and Resource,Shanxi University,Taiyuan 030006,Shanxi,China

出　　处：《Journal of Energy Chemistry》2024年第1期10-27,I0001,共19页能源化学（英文版）

基　　金：supported by the Tianjin Science and Technology support key projects (20JCYBJC01420)。

摘　　要：The electrochemical carbon dioxide reduction reaction(eCO_(2)RR),which converts CO_(2)into various hydrocarbons or alcohols,has been extensively researched because it promises a sustainable energy economy.However,only copper(Cu)can currently achieve stable and efficient hydrocarbon conversion in the eCO_(2)RR.Therefore,understanding the catalytic mechanisms and summarizing the research progress on synthesis strategies of Cu catalysts are essential for the eCO_(2)RR.This paper reviews Cu catalysts with different surface states of Cu catalysts:oxide-derived Cu,Cu nanoparticles,Cu single atoms,and Cu nanoclusters.It then reviews the development and progress of different Cu-catalyst preparation methods in recent years,focusing on the activity and selectivity of materials.Besides revealing the tendencies of catalytic selection and deep reactive mechanisms of Cu catalysts with four different surface states,this review can guide the subsequent construction of catalysts and provides an understanding of catalytic mechanisms.

关 键 词：eCO_(2)RR Oxide-derived Cu Cu nanoparticles Cu single atoms Cu nanoclusters 

分 类 号：TQ426[化学工程]