Synthesis and applications of lanthanoid complexes of pentadentate and hexadentate N_(5) and N_(6) macrocycles:A review  

作　　者：Julio Corredoira-Vázquez Cristina González-Barreira Paula Oreiro-Martínez Ana M.García-Deibe Jesús Sanmartín-Matalobos Matilde Fondo 

机构地区：[1]Departamento de Química Inorganica,Facultade de Química,Universidade de Santiago de Compostela,Campus Vida,15782,Santiago de Compostela,Spain [2]Phantom-g,CICECO-Aveiro Institute of Materials,Department of Physics,University of Aveiro,3810-193,Aveiro,Portugal [3]Institute of Materials(iMATUS),Universidade de Santiago de Compostela,15782,Santiago de Compostela,Spain

出　　处：《Journal of Rare Earths》2024年第1期1-15,I0001,共16页稀土学报（英文版）

基　　金：Xunta de Galicia for his postdoctoral fellowship(ED481B-2022-068);the Fundación Segundo Gil Dávila for her PhD fellowship。

摘　　要：In this paper,the lanthanoid complexes of N_(5) and N_(6) macrocycle ligands,without pendant arms or additional heteroatoms,are surveyed.This review covers the period from 2015 to the current date,since in 2014 Schiff base macrocyclic ligands incorporating the pyridine moiety,and their complexes,were revised,and in 2015 the chemistry of pentaaza macrocycle ligands with rare earth metals was also summarized.Porphyrin and phthalocyanine ligands are not included in this review,which primarily focuses on complexes with Schiff bases and amines without pendant arms or any additional donor other than nitrogen.The synthetic methods,structural characterization,based on single X-ray crystal data,and properties of the lanthanoid complexes,with special attention to magneto-structural correlations,are presented herein.

关 键 词：LANTHANOID N_(5) N_(6)macrocycle Coordination chemistry CHIRALITY Biological activity Molecule magnet 

分 类 号：O641.4[理学—物理化学]