高居里点BaTiO_(3)基无铅正温度系数热敏陶瓷的研究进展  

Research Progress on High Curie Point BaTiO_(3) Based Lead-Free Positive Temperature Coefficient Thermosensitive Ceramics

作　　者：李诗恒 岳宇昕 张永丽 曾江涛 杜刚 张伟 沈十林 曾涛[2] LI Shiheng;YUE Yuxin;ZHANG Yongli;ZENG Jiangtao;DU Gang;ZHANG Wei;SHEN Shilin;ZENG Tao(School of Energy and Materials,Shanghai Polytechnic University,Shanghai 201209,China;Shanghai Key Laboratory of Engineering Materials Application and Evaluation,Shanghai Research Institute of Materials Co.,Ltd.,Shanghai 200437,China;Logistics Engineering College,Shanghai Maritime University,Shanghai 201306,China;Shanghai Engineering Research Center of Electronic Circuit Intelligent Protection,Shanghai 201202,China;Shanghai Wayon Electronics Co.,Ltd.,Shanghai 201202,China)

机构地区：[1]上海第二工业大学能源与材料学院,上海201209 [2]上海材料研究所有限公司,上海市工程材料应用与评价重点实验室,上海200437 [3]上海海事大学物流工程学院,上海201306 [4]上海电子线路智能保护工程技术研究中心,上海201202 [5]上海维安电子有限公司,上海每201202

出　　处：《机械工程材料》2023年第12期1-5,共5页Materials For Mechanical Engineering

基　　金：上海市国际科技合作项目(20520730600)。

摘　　要：正温度系数(PTC)热敏材料是一种对温度十分敏感的半导体材料,其中BaTiO_(3)基PTC热敏陶瓷应用最为广泛。为满足高温使用需求与无铅化绿色环保要求,高居里点BaTiO_(3)基无铅PTC热敏陶瓷受到了极大的关注。介绍了几种常见的高居里点BaTiO_(3)基无铅PTC热敏陶瓷体系,综述了其改性方法,包括施主掺杂、受主掺杂、工艺改进等,阐述了该材料目前的不足,并对其今后的发展方向进行了展望。The positive temperature coefficient(PTC) thermosensitive material is a semiconductor material that is very sensitive to temperatures, among which the BaTiO_(3) based PTC thermosensitive ceramic is the most widely used. In order to meat the needs of high temperature use and lead-free green environmental protection requirements, the high Curie point BaTiO_(3) based lead-free PTC thermosensitive ceramics has received great attention. Several common high Curie BaTiO_(3) based lead-free PTC thermosensitive ceramics are introduced, and the modification methods, including donor doping, acceptor doping and process improvement, are reviewed. The current shortcomings of the materials are described, and the future development direction is prospected.

关 键 词：高居里温度 PTC BaTiO_(3) 无铅 

分 类 号：TM283[一般工业技术—材料科学与工程]