高效液相色谱法测定生活用纸中甲醛、乙二醛、戊二醛的迁移量  

Determination of migration of formaldehyde,glyoxal,and glutaraldehyde in household paper by high performance liquid chromatography

作　　者：肖湾 顾钰华[1] 孙多志[1] 周呈 Xiao Wan;Gu Yuhua;Sun Duozhi;Zhou Cheng(Shanghai Institute of Quality Inspection and Technical Research,Shanghai 201114,China)

机构地区：[1]上海市质量监督检验技术研究院,上海201114

出　　处：《分析仪器》2024年第1期21-25,共5页Analytical Instrumentation

基　　金：上海市科学技术委员会研发公共服务平台建设项目(14DZ2293000)。

摘　　要：建立了高效液相色谱测定生活用纸中的甲醛、乙二醛、戊二醛含量的方法,优化了色谱分析的参数,考察了不同的衍生条件,包括检测波长的选择、流动相的选择、衍生反应酸的选择、衍生反应试剂的用量、衍生反应溶剂的用量、衍生反应时间对衍生产物的影响,并对衍生物的稳定性进行了考察。本方法中甲醛、乙二醛、戊二醛在5mg/L~25mg/L范围内线性相关系数均大于0.995,方法检出限分别为0.01135mg/dm2、0.02462mg/dm^(2)、0.04841mg/dm^(2),高、中、低3个水平加标回收率在90.6%~99.0%之间,相对标准偏差范围为0.36%~2.88%,可满足生活用纸中甲醛、乙二醛、戊二醛检测要求。The chromatographic analysis parameters are optimized,and different derivative conditions are investigated,including the selection of detection wavelength,mobile phase,derivative reaction acid,amount of derivative reaction reagent,amount of derivative reaction solvent,and the effect of derivative reaction time on the derivative products.The stability of the derivatives is also investigated.In this method,the linear correlation coefficients of formaldehyde,glyoxal,and glutaraldehyde are all greater than 0.995 in the range of 5mg/L to 25mg/L.The detection limits of the method are 0.01135mg/dm^(2)、0.02462mg/dm^(2)、0.04841mg/dm^(2) and the recovery rates of high,medium,and low levels are between 90.6%and 99.0%.The relative standard deviation range is from 0.36%to 2.88%,which meet the detection requirements for formaldehyde,glyoxal,and glutaraldehyde in household paper.

关 键 词：液相色谱法 甲醛 乙二醛 戊二醛 生活用纸 

分 类 号：TS761.6[轻工技术与工程—制浆造纸工程] O657.71[理学—分析化学]