Design,synthesis and applications of functional zirconium-based metal-organic frameworks  

作　　者：Le Shi Zhenning Yang Fanrui Sha Zhijie Chen 

机构地区：[1]Stoddart Institute of Molecular Science,Department of Chemistry,Zhejiang University,Hangzhou 310058,China [2]Zhejiang-Israel Joint Laboratory of Self-Assembling Functional Materials,ZJU-Hangzhou Global Scientific and Technological Innovation Center,Zhejiang University,Hangzhou 311215,China [3]Department of Chemistry and International Institute for Nanotechnology,Northwestern University,Evanston,Illinois 60208,United States

出　　处：《Science China Chemistry》2023年第12期3383-3397,共15页中国科学（化学英文版）

基　　金：support by the National Natural Science Foundation of China (22201247);the startup funding from Zhejiang University。

摘　　要：Zirconium-based metal-organic frameworks(Zr-MOFs)have been explored for applications including but not limited to water adsorption,gas storage and separation,heterogeneous catalysis,and chemical sensing.Zr-MOFs serve as a major class of functional MOFs thanks to their high thermal,chemical and hydrolytic stability,large surface area,and tunable structures with the versatile connectivity.In this work,we highlight the design and synthesis of zirconium-based MOFs as well as their applications.Specifically,we demonstrate how reticular chemistry can direct the rational design and synthesis of functional ZrMOFs and describe their structure–property relationship.In addition,we feature synthetic strategies,including isoreticular expansion,linker functionalization,node functionalization,and defect engineering,as toolkits to construct tailored material for specific applications.

关 键 词：metal-organic frameworks Zr-MOFs reticular chemistry structure–property relationship 

分 类 号：TB34[一般工业技术—材料科学与工程]