羰基合成与羰基化催化剂的研究进展及工业化应用  

Research and application progress of catalysts for carbonyl synthesis and industrial carbonylation

作　　者：高晓奇 赵伟 张静 任珂 张玉玲 岳广明 Gao Xiaoqi;Zhao Wei;Zhang Jing;Ren Ke;Zhang Yuling;Yue Guangming(Shaanxi Xinghua(Group)Corporation Ltd.,Xingping 713100,China;Yanchang Zhongke(Dalian)Energy Technology Corporation Ltd.,Dalian 116085,China;Henan Liyuan Xinneng Technology Corporation Ltd.,Anyang 455000,China)

机构地区：[1]陕西兴化集团有限责任公司,陕西兴平713100 [2]延长中科(大连)能源科技股份有限公司,辽宁大连116085 [3]河南利源新能科技有限公司,河南安阳455000

出　　处：《煤炭与化工》2024年第1期135-139,共5页Coal and Chemical Industry

摘　　要：羰基合成反应在催化化学中扮演着重要角色,并通过新合成方法和新物质的多样性创制成为生产多种含氧化合物及高附加值产品的重要途径。而恰当的催化体系是羰基合成工艺和技术的关键,也是羰基化反应实现工业化的研究重点。首先从不同的反应底物、不同的羰基来源以及不同的反应类型等方面对羰基合成反应及研究进展进行概述,然后从以金属和非金属为活性中心的角度对羰基化催化剂的应用及研究进展进行阐述,最后列举了几种典型的羰基合成反应及羰基化催化剂在工业上的应用。Carbonyl synthesis reaction plays an important role in catalytic chemistry,and through the new synthesis methods and the diversity of new substances become a significant pathway for produce diverse oxygen-containing compounds and high-value-added products.The selection of an appropriate catalytic system is the key to the process and technology of carbonyl synthesis,and it is also the focus of research to realize industrialization of carbonyl reaction.Firstly,this dissertation the carbonyl synthesis reaction and research progress from the aspects of different reaction substrates,different carbonyl sources and different reaction types were summarized,then the application and research progress of carbonylation catalysts from the perspective of metal and non-metal active centers were expounded,and finally several typical carbonyl synthesis reactions and industrial applications of carbonylation catalysts were enumerated.

关 键 词：羰基合成化学 羰基化催化剂 金属活性中心 羰基金属配合物 非金属活性中心 分子筛 

分 类 号：TQ23[化学工程—有机化工]