A Highly Efficient Ni/Al_(2)O_(3)-LaO_(x) Catalyst for the Reductive Amination of Furfural to Furfurylamine:the Promoting Effect of La  

作　　者：YANG Yinze ZHANG Liyan ZHOU Leilei CHENG Haiyang ZHAO Fengyu 

机构地区：[1]State Key Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,P.R.China [2]School of Applied Chemistry and Engineering,University of Science Technology of China,Hefei 230026,P.R.China [3]Jilin Province Key Laboratory of Green Chemistry and Process,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,P.R.China

出　　处：《Chemical Research in Chinese Universities》2024年第1期36-46,共11页高等学校化学研究（英文版）

基　　金：the National Key Research and Development Program of China(No.2022YFA1504901);the National Natural Science Foundation of China(No.NSFC 22072142);the Science and Technology Development Program of Jilin Province,China(No.YDZJ202301ZYTS539).

摘　　要：The reductive amination of furfural to furfurylamine is an important and still challenging topic in the field of biomass conversion. In this work, we prepared a series of Ni/Al_(2)O_(3)-LaO_(x) catalysts by co-precipitation method, the role of La played in promoting the catalytic performances of reductive amination furfural was discussed based on the changes in the electronic state of Ni species, acidity, and Ni particle size. The catalytic activity and the selectivity of furfurylamine are highly dependent on the surface properties and the structure of the catalyst. The addition of La promoted the amount of strong acidic sites and the H2dissociation and spillover on the surface, thus inducing the improvement of the catalytic activity and furfurylamine selectivity. The Ni/Al_(2)O_(3)-0.5LaO_(x)catalyst with suitable acid sites gave a high yield of furfurylamine (94.9%) under mild reaction conditions. Moreover, the catalyst could be recycled five times without significant loss in activity. The Ni/Al_(2)O_(3)-LaO_(x) catalyst is of great promise in the production of amines via reductive amination reaction.

关 键 词：Reductive amination FURFURAL Nickel catalyst FURFURYLAMINE LANTHANUM 

分 类 号：O64[理学—物理化学]