Zeolite-confined Fe-site Catalysts for the Hydrogenation of CO_(2) to Produce High-value Chemicals  

作　　者：HAN Xiaoyang XIA Huicong TU Weifeng WEI Yifan XUE Dongping LI Minhan YAN Wenfu ZHANG Jia-Nan HAN Yi-Fan 

机构地区：[1]College of Materials Science and Engineering,Zhengzhou University,Zhengzhou,450001,P.R.China [2]State Key Laboratory of Coking Coal Resources Green Exploitation,Zhengzhou University,Zhengzhou,450001,P.R.China [3]Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education,School of Chemical Engineering,Zhengzhou University,Zhengzhou,450001,P.R.China [4]State Key Laboratory of Inorganic Synthesis and Preparative Chemistry and College of Chemistry,Jilin University,Changchun,130012,P.R.China [5]State Key Laboratory of Chemical Engineering,East China University of Science and Technology,Shanghai,200237,P.R.China

出　　处：《Chemical Research in Chinese Universities》2024年第1期78-95,共18页高等学校化学研究（英文版）

基　　金：the National Natural Science Foundation of China(Nos.U22A20107,U1967215,22078307,22208314,22278379,22238003,and 22002008);the Science and Technology R&D Program Joint Fund Project of Henan Provincial,China(No.222301420001);the Distinguished Young Scholars Innovation Team of Zhengzhou University,China(No.32320275);the Postgraduate Education Reform Project of Henan Province,China(No.2021SJGLX093Y);the National Funded Postdoctoral Researcher Program,China(No.GZC20232382);the Key Research Projects of University in Henan Province,China(No.24A150041).

摘　　要：Zeolite-confined Fe-site catalysts(ZFCs)have emerged as superior materials for sustainably producing high-value chemicals through CO_(2) hydrogenation,owing to their adaptable framework,customizable composition,and thermal robustness.They excel in activating,adsorbing,and converting CO_(2) with remarkable efficiency and consistency in performance.This has sparked a surge in research interest in recent years.The review delves into the latest advancements in CO_(2) catalytic hydrogenation to olefins,alcohols,aromatics,and other liquid hydrocarbons,examining the synthesis,modification tactics,and the correlation between structure and performance across various ZFCs.Additionally,it underscores the pivotal factors affecting performance and sheds light on the mechanisms behind selectivity control in the CO_(2) hydrogenation process facilitated by ZFCs.To conclude,it presents pressing challenges and strategic recommendations to inspire the development of high-performance,durable ZFCs for CO_(2) hydrogenation applications.

关 键 词：Zeolite-confined Fe-site catalyst CO_(2) hydrogenation Modification strategy High-value chemical 

分 类 号：O64[理学—物理化学]