微/纳米反应器及纳微界面催化反应机理  

Micro-nano reactors and their catalytic mechanism at the micro/nano interface

作　　者：李海涛 田江立 刘健[1,3] Haitao Li;Jiangli Tian;Jian Liu(State Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China;Center of Materials Science and Optoelectronics Engineering,University of Chinese Academy of Sciences,Bejing 100049,China;School of Chemistry and Chemical Engineering,Inner Mongolia University,235 West University Stree,Hoot10021,China)

机构地区：[1]中国科学院大连化学物理研究所,催化基础国家重点实验室,大连116023 [2]中国科学院大学材料科学与光电技术学院,北京100049 [3]内蒙古大学化学化工学院,呼和浩特010021

出　　处：《中国科学：化学》2024年第1期21-34,共14页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:22279139);中国博士后科学基金(编号:2022M713084)资助项目。

摘　　要：学习自然是科学创造和科学生产的最佳驱动力.微/纳米反应器作为介观尺度下人工细胞仿生微纳结构材料代表,其微观形貌具有界限明显的中空腔室、丰富的纳米孔道等结构特征,在多相催化、能源存储和生物医药等领域具有重要的潜在应用价值.本文系统总结了微/纳米反应器定制策略开发、活性位精准锚定、纳米反应器效应探究及应用等方面的进展,重点集中在本课题组的代表性成果,以期为新型功能微纳米材料研制、介观尺度空间/界面反应过程及纳微界面理论探索提供良好的借鉴.Learning from nature is the best drive for scientific creation and production.Micro-nano reactor,as a representative cell mimic at the mesoscale,has structural features of well-defined chambers and abundant channels,sparking tremendous interest in heterogeneous catalysis,energy storage,and biomedical engineering.This paper systematically summarizes the original achievements of our team in the development of novel synthesis strategies for micro-nano reactors,precise anchoring active sites,clarifying advantageous effects,and characteristic applications.It holds a potential reference for designing functional materials and exploring micro/nano interfacial processes and theories.

关 键 词：人工细胞 仿生 微/纳米反应器 中空/多孔材料 纳微界面 

分 类 号：O643.32[理学—物理化学] TB383.1[理学—化学]