丙烯腈亲核加成反应研究进展  

Research Progress in Nucleophilic Addition of Acrylonitrile

作　　者：俞鸿博 孙文瑄 魏微 鄢冬茂[1] 李书龙 何威葳 孙成明 于海 宁绍宇 YU Hongbo;SUN Wenxuan;WEI Wei;YAN Dongmao;LI Shulong;HE Weiwei;SUN Chengming;YU Hai;NING Shaoyu(Shenyang Research Institute of Chemical Industry Co.,Ltd.,Shenyang 110021,Liaoning China;Luxi Chemical Group Co.,Ltd.,Liaocheng 252211,Shandong China;Sinochem(Shenyang)Advanced Materials Technology Co.Ltd.,Shenyang 110037,Liaoning China;Chonfar Engineering and Technology Co.,Ltd.,Changsha 410083,Hunan China)

机构地区：[1]沈阳化工研究院有限公司,沈阳110021 [2]鲁西化工集团股份有限公司,聊城252211 [3]沈阳中化新材料科技有限公司,沈阳110037 [4]中蓝长化工程科技有限公司,长沙410083

出　　处：《染料与染色》2023年第6期24-30,共7页Dyestuffs and Coloration

摘　　要：本文综述了丙烯腈和脂肪族胺、芳香胺、α-β不饱和化合物的亲核加成反应研究进展及其机理,总结了胺化工艺的规律,对比了几种催化剂对胺化反应的影响。对此类胺化反应进行了展望。Research progress and mechanism of nucleophilic addition of acrylonitrile with aliphatic amines,with aromatic amines and with α-β unsaturated compounds were reviewed.Process of amination reaction aminated by acrylonitrile were summarized.Effects of some catalysts on amination reaction were compared.Prospects of the amination reaction were looked forward.

关 键 词：丙烯腈 胺化反应 亲核加成 

分 类 号：TQ612.1[化学工程—精细化工]