经由可逆碳碳键断裂的去消旋化反应  

Deracemization through C-C bond manipulation

作　　者：许言 董广彬 Yan Xu;Guangbin Dong(Beijing National Laboratory for Molecular Sciences(BNLMS),Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China;Department of Chemistry,University of Chicago,Chicago IL 60637,USA)

机构地区：[1]Beijing National Laboratory for Molecular Sciences(BNLMS),Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China [2]Department of Chemistry,University of Chicago,Chicago IL 60637,USA

出　　处：《Science Bulletin》2024年第3期285-287,共3页科学通报（英文版）

摘　　要：Asymmetric catalysis has proven remarkably successful in achieving enantioselective control during the construction of new stereogenic centers.However,the challenge of achieving chiral enrichment at pre-existing stereogenic centers,without introducing additional molecular variations,remains a rare and intriguing pursuit known as asymmetric stereochemical editing[1–3].

关 键 词：CATALYSIS STEREO PURSUIT 

分 类 号：O621.25[理学—有机化学]