氧化加成形成稳定的Cu(Ⅲ)络合物  

Stable oganocopper(III)complexes generated via oxidative addition

作　　者：殷凌峰 刘巍 Lingfeng Yin;Wei Liu(Department of Chemistry,University of Cincinnati,Cincinnati OH 45221,USA)

机构地区：[1]Department of Chemistry,University of Cincinnati,Cincinnati OH 45221,USA

出　　处：《Science Bulletin》2024年第3期288-289,共2页科学通报（英文版）

基　　金：This work was supported by the National Science Foundation,USA(CHE-2237757).

摘　　要：Organic chemists now have a much better understanding of the mechanism of copper catalysis,thank to the recent work by Shen,Hartwig,and Xue published in Science [1].In this work,Shen’s team demonstrated,that well-defined,isolable organocopper(Ⅲ) complexes can be synthesized through the oxidative addition of alkyl electrophiles to copper(1) species.This elemental step has been widely proposed as a key step in copper-catalyzed cross-coupling of alkyl electrophiles (Fig.1).

关 键 词：COPPER 氧化加成 OXIDATIVE 

分 类 号：O641.4[理学—物理化学]