MOFs基复合材料在生物柴油合成中的应用进展  

Application progress of MOFs-based composite materials for biodiesel production

作　　者：张秋云 李伟华 赵永婷 张玉涛 ZHANG Qiuyun;LI Weihua;ZHAO Yongting;ZHANG Yutao(Key Laboratory of Agricultural Resources and Environment in High Education Institute of Guizhou Province,School of Chemistry and Chemical Engineering,Anshun University,Anshun 561000,China)

机构地区：[1]安顺学院化学化工学院贵州省高等学校农业资源与环境研究重点实验室,贵州安顺561000

出　　处：《石油化工》2024年第2期240-250,共11页Petrochemical Technology

基　　金：国家自然科学基金项目(22262001);贵州省高等学校多孔材料与绿色催化创新团队项目(黔教技[2023]086号);贵州省高等学校农业资源与环境研究重点实验室项目(黔教技[2023]025)。

摘　　要：金属有机框架(MOFs)材料由于高比表面积、多孔性、化学可调性及丰富的活性位点等功能特性,在多相催化领域得到广泛应用。针对MOFs基复合材料在催化合成生物柴油中的应用,综述了MILs基、ZIFs基、UiO基、MOFs衍生物基等四类复合材料的制备、特性及催化行为等。对MOFs基复合材料面临的机遇和挑战进行了展望。Metal-organic frameworks(MOFs)materials have been widely used in thefield of multiphase catalysis due to their high specific surface area,porosity,chemical tunability,and abundant active sites.This review focuses on the application of MOFs-based composite materials for catalytic synthesis of biodiesel,and summarizes the design,preparation,physicochemical properties,and catalytic activity of four types of MOFs-based composite materials,including MILs-based,ZIFs-based,UiO-based,MOFs derivatives-based composites.The challenges and prospects of MOFs-based composite materials are also discussed.

关 键 词：金属有机框架 复合材料 催化剂 生物柴油 酯化 酯交换 

分 类 号：TQ426[化学工程]