PVDF膜接触器在电厂含氨废水处理中的应用研究  

Application research of PVDF membrane contactor in the treatment of ammonia-containing wastewater in power plants

作　　者：吕佳慧 戴洁 施国忠 岑易 徐浩然 冯向东 张林 LYU Jiahui;DAI Jie;SHI Guozhong;CEN Yi;XU Haoran;FENG Xiangdong;ZHANG Lin(Zhejiang Energy Group R&D Co.,Ltd.,Hangzhou 311121,China;Zhejiang Zheneng Zhenhai Power Generation Co.,Ltd.,Ningbo 315000,China;Engineering Research Center for New Industrial Water Resources of Zhejiang Province,Hangzhou 311121,China;Zhejiang Key Laboratory of Thermal Power Generation Energy Efficiency and Pollutant Control Technology,Hangzhou 311121,China;College of Chemical and Biological Engineering,Zhejiang University,Hangzhou 310058,China)

机构地区：[1]浙江浙能技术研究院有限公司,杭州311121 [2]浙江浙能镇海发电有限责任公司,宁波315000 [3]工业新水源技术浙江省工程研究中心,杭州311121 [4]浙江省火力发电高效节能与污染物控制技术研究重点实验室,杭州311121 [5]浙江大学化学工程与生物工程学院,杭州310058

出　　处：《膜科学与技术》2024年第1期123-129,共7页Membrane Science and Technology

基　　金：浙江省“领雁”计划项目(2022C03048)。

摘　　要：燃煤电厂含氨废水具有水量大、氨氮浓度高、水质波动大的特点,常规脱氨工艺处理困难.本文采用PVDF膜接触器处理燃煤电厂高浓含氨废水,考察了膜接触器类型、水侧流量、气侧真空度、气液接触面积、进水水质等因素对脱氮效率的影响.结果表明,基于PVDF膜接触器的气液分离工艺,能够将高浓含氨废水中的氨氮浓度由1 250 mg/L降至300 mg/L以下;外压式和内压式膜接触器都有理想的应用效果;提高膜接触器水侧流量、气侧真空度能够有效提高NH3传质效率;增大传质膜面积能够显著提升循环液氨氮脱除率.提出了分离NH3在燃煤电厂的多种资源化回用途径,为膜接触器的工程化应用提供参考.The ammonia-containing wastewater from coal-fired power plants has the characteristics of large water volume,high ammonia-nitrogen concentration,and large water quality fluctuations,making conventional ammonia removal processes difficult to treat.In this paper,PVDF membrane contactor was used to treat high-concentration ammonia-containing wastewater from coal-fired power plants.The effects of membrane contactor type,water flow,gas vacuum,gas-liquid contact area and influent water quality on nitrogen removal efficiency were investigated.The results show that the gas-liquid separation process based on PVDF membrane contactors can reduce the concentration of ammonia nitrogen in high-concentration ammonia containing wastewater from 1250 mg/L to below 300 mg/L.Both external and internal pressure membrane contactors have ideal application effects;The mass transfer efficiency of NHs can be effectively improved by increasing the flow rate of water side and the vacuum degree of air side;Increasing the mass transfer membrane area can significantly improve the removal rate of ammonia nitrogen in circulating liquid.Multiple resource utilization pathways for separating NH in coal-fired power plants have been proposed,which provides reference for the engineering application of membrane contactors.

关 键 词：膜接触器 含氨废水 燃煤电厂 脱氮通量 聚偏氟乙烯 

分 类 号：TQ028[化学工程] X703[环境科学与工程—环境工程]