金属有机骨架(MOFs)基复合质子交换膜的研究进展  

Research progress of metal-organic frameworks(MOFs)based composite proton exchange membranes

作　　者：李磊[1,2] 王园园[1] 魏国兰 LI Lei;WANG Yuanyuan;WEI Guolan(School of Textile Science and Engineering,Tiangong University,Tianjin 300387,China;State Key Laboratory of Separation Membranes and Membrane Processes,Tiangong University,Tianjin 300387,China)

机构地区：[1]天津工业大学纺织科学与工程学院,天津300387 [2]天津工业大学分离膜与膜过程国家重点实验室,天津300387

出　　处：《天津工业大学学报》2024年第1期17-27,共11页Journal of Tiangong University

基　　金：国家自然科学基金资助项目(51802216);中国博士后科学基金面上项目(2022M720974);海南省博士后研究项目(282427)。

摘　　要：近年来,金属有机骨架(MOFs)材料由于具有超大的比表面积和丰富的孔道结构,作为一种新型的质子导体在质子交换膜中的应用受到越来越多的关注。随着研究的不断深入,为进一步提升MOFs复合质子交换膜的各项性能,MOFs材料在质子交换膜中的物理形态逐渐由颗粒状向连续相发展,MOFs材料的组分也呈现出由单一组分到双组分的发展态势。本文以质子交换膜中MOFs材料的物理形态为主线,将其划分为MOFs晶体/聚合物质子交换膜、第三相增强MOFs/聚合物复合质子交换膜和MOFs纳米纤维/聚合物复合质子交换膜,全面综述了MOFs材料在质子交换膜中的研究进展,并对MOFs复合质子交换膜的发展方向进行了展望。In recent years,metal-organic frameworks(MOFs) have attracted more and more attention as a new type of proton conductor in proton exchange membranes due to their large specific surface area and abundant pore structures.With the continuous deepening of research,to further improve the performance of MOFs composite proton exchange membrane,the physical morphology of MOFs materials in the proton exchange membrane has gradually developed from granular to continuous phase,and the composition of MOFs materials has also evolved from a single component to dual component.Based on the physical morphology of MOFs materials in proton exchange membranes,this paper divides them into MOFs crystal/polymer proton exchange membranes,the third phase reinforced MOFs/polymer composite proton exchange membranes,and MOFs nanofiber/polymer composite proton exchange membranes,comprehensively summarizes the research progress of MOFs materials in proton exchange membranes,and prospects the development direction of MOFs composite proton exchange membranes.

关 键 词：金属有机框架 复合质子交换膜 质子传导率 燃料电池 

分 类 号：TM912[电气工程—电力电子与电力传动]