甲醇对于PEI-SBA固态胺制备及其性能的影响  

Effect of Methanol on the Preparation and Performance of PEI-SBA Solid Amine

作　　者：胡海涛 郑岳青[1] 林贻超 HU Hai-tao;ZHENG Yue-qing;LIN Yi-chao(School of Materials Science and Chemical Engineering,Ningbo University,Ningbo 315211,China;Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province,Ningbo Institute of Materials Technology and Engineering,Chinese Academy of Sciences,Ningbo 315201,China)

机构地区：[1]宁波大学材料科学与化学工程学院,浙江宁波315211 [2]中国科学院、宁波材料技术与工程研究所、浙江省先进燃料电池与电解池技术重点实验室,浙江宁波315201

出　　处：《化学试剂》2024年第3期33-38,共6页Chemical Reagents

基　　金：浙江省‘尖兵’‘领雁’研发攻关计划项目(2022C01029)。

摘　　要：固态胺材料具有优异的二氧化碳(CO_(2))选择吸附性能,是一类潜在的CO_(2)捕集材料。作为一种重要的固态胺材料,SBA-15负载聚乙烯亚胺(PEI-SBA-15)由于原材料较为廉价且性能优异受到了大量的关注。PEI-SBA-15的制备过程需要采用甲醇溶剂,而溶剂使用量对于其CO_(2)吸附性能的影响尚无系统研究。系统研究了溶剂使用量对SBA-15负载聚乙烯亚胺的CO_(2)吸附性能的影响。研究结果表明,可以同时实现提升CO_(2)吸附性能和CO_(2)/N_(2)选择性和大幅降低甲醇的使用量。对于降低PEI-SBA-15的制备成本以及提升制备过程环保性具有重要意义。Solid amine materials have excellent carbon dioxide(CO_(2))selective adsorption properties and are potential materials for CO_(2) capture.As an important type of solid amine material,polyethyleneimine-loaded SBA-15(PEI-SBA-15)has attracted a lot of attention due to its relatively low cost of raw materials and excellent performance.The preparation process of PEI-SBA-15 requires the use of methanol as a solvent,but the influence of solvent usage on its CO_(2) adsorption performance has not been systematically studied.Given this,this work systematically investigated the effect of solvent usage on the CO_(2) adsorption performance of SBA-15 loaded with polyethyleneimine.The research results showed that it was possible to simultaneously improve CO_(2) adsorption performance,and CO_(2)/N_(2) selectivity,and significantly reduce the usage of methanol.This research work is of great significance for reducing the preparation cost of PEI-SBA-15 and improving the environmental friendliness of the preparation process.

关 键 词：SBA-15分子筛 CO_(2)吸附 固态胺 聚乙烯亚胺 溶剂作用 碳中和 

分 类 号：TQ-9[化学工程]