Electrochemical radical-polar crossover:a radical approach to polar chemistry  

作　　者：Zhoumei Tan Haonan Zhang Kun Xu Chengchu Zeng 

机构地区：[1]Faculty of Environment and Life,Beijing University of Technology,Beijing,100124,China

出　　处：《Science China Chemistry》2024年第2期450-470,共21页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China (22171015,22271009);the Beijing Natural Science Foundation (2222003);the Beijing Municipal Education Committee Project (KZ202110005003,KM202110005006)。

摘　　要：Radical-polar crossover(RPC) reaction bridges the gap between one-and two-electron reactivities,thus providing an ideal solution to overcome the limitations of both radical and polar chemistry.In this manifold,organic electrochemistry provides a uniquely facile strategy to access a diverse array of radical intermediates,thus broadening the chemical space of the RPC concept.This review highlights the synthetic advances in the field of electrochemical RPC reactions since 2020,with an emphasis on the substrate scope,reaction limitation and mechanistic aspect.The related RPC reactions are categorized as netoxidative,net-reductive,or redox neutral transformations.

关 键 词：ELECTROSYNTHESIS radical-polar crossover radical chemistry polar chemistry alkene functionalization 

分 类 号：O646[理学—物理化学]