Design and preparation of a crosslinkable,oil-resistant,and bio-based elastomer from fumarate  

作　　者：Hui Yang Haijun Ji Xinxin Zhou Shihan Yang Liwei Li Chaoying Sun Weiwei Lei Runguo Wang Liqun Zhang 

机构地区：[1]Beijing State Key Laboratory of Organic-Inorganic Composites&Beijing Laboratory of Biomedical Materials,Beijing University of Chemical Technology,Beijing,100029,China [2]Hubei Key Laboratory of Polymer Materials,Faculty of Materials Science and Engineering,Hubei University,Wuhan,430062,China

出　　处：《Science China Chemistry》2024年第2期622-631,共10页中国科学（化学英文版）

基　　金：supported by the National Key Research and Development Program of China (2022YFC2104700);the National Natural Science Foundation of China (52273003,51988102)。

摘　　要：Poly(diethyl fumarate-co-methoxyethyl acrylate-co-vinyl chloroacetate)(PDEFMV),a novel bio-based elastomer with a saturated structure,was synthesized via redox emulsion polymerization.The glass-transition temperatures of PDEFMV,adjusted through the variation of the diethyl fumarate-to-methoxyethyl acrylate feeding ratio,ranged from-36.1 to-14.8 ℃.The number-average molecular weights of PDEFMV ranged from 384,000 to 46,000 g/mol.In designing the molecular structure,vinyl chloroacetate was used to provide active sites for subsequent vulcanization and crosslinking.The active chlorine groups within the PDEFMV chain reacted with the crosslinking agent trithiocyanuric acid under high temperature and pressure to form a nonsulfur crosslinked three-dimensional network structure.To achieve the desired properties,carbon black(CB,N330) was incorporated to reinforce PDEFMV,leading to the formation of PDEFMV/CB composites.A comprehensive study was conducted on the high-temperature oil resistance of PDEFMV/CB composites.Following immersion in IRM903 oil at temperatures of 150 and 200 ℃ for 72 h,the mass and volume changes in PDEFMV/CB were lower than those observed in commercially available acrylate rubber(AR)/CB,indicating that PDEFMV exhibited superior oil resistance.Furthermore,the aging characteristics and mechanisms of oil resistance in the PDEFMV/CB and AR/CB composites were investigated at different temperatures(150,200,and 250 ℃).The results provide insights into the operational temperature ranges suitable for PDEFMV/CB and offer valuable guidance for potential industrial applications.

关 键 词：diethyl fumarate molecular design bio-based elastomer solvent-free synthetic route high-temperature oil resistance 

分 类 号：TQ225.24[化学工程—有机化工]