高效柔性钙钛矿太阳电池的研究进展  

Research Progress on High Efficiency Flexible Perovskite Solar Cells

作　　者：蒋君 王梦辉 杨攻旅 胡宏伟 丁建宁 袁宁一 Jiang Ju;Wang Menghui;Yang Gonglu;Hu Hongwei;Din Jianning;Yuan Ningyi(School of Materials Science and Engineering,Changzhou University,Changzhou 213164,China;Jiangsu Collaborative Innovation Center for Photovoltaic Science and Engineering,Changzhou University,Changzhou 213164,China;School of Mechanical Engineering,Jiangsu University,Zhenjiang 212013,China;Yangzhou Technology Innovation Research Center for Carbon Neutrality,Yangzhou University,Yangzhou 225009,China)

机构地区：[1]常州大学材料科学与工程学院,江苏常州213164 [2]常州大学江苏省光伏科学与工程协同创新中心,江苏常州213164 [3]江苏大学机械工程学院,江苏镇江212013 [4]扬州大学扬州碳中和技术创新研究中心,江苏扬州225009

出　　处：《半导体技术》2024年第3期201-217,共17页Semiconductor Technology

基　　金：江苏高校自然科学研究面上项目(22KJB430016);江苏省碳达峰碳中和科技创新专项资金项目(BE2022610)。

摘　　要：钙钛矿太阳电池(PSC)具有高光电转换效率(PCE)、低成本、易采用溶液法制备等特点,在发展轻薄、便携的柔性太阳电池方面有独特优势,可用于可穿戴设备、光伏建筑等领域。由于在柔性衬底上沉积均匀和高质量的钙钛矿薄膜颇具挑战性,目前,单结柔性钙钛矿太阳电池的PCE虽已经达到24.08%,但仍落后于刚性钙钛矿太阳电池(认证PCE为26.1%);此外,柔性钙钛矿薄膜在制备和弯曲循环过程中会不可避免地产生晶界裂纹,这也为柔性钙钛矿太阳电池的稳定性和可靠性带来巨大挑战。系统地评述了提升柔性钙钛矿太阳电池PCE和稳定性的研究进展,从柔性衬底、晶粒调控、晶界增强、界面钝化及结构优化等不同角度进行了归纳总结,并对柔性钙钛矿太阳电池未来发展存在的问题和挑战进行了展望。Characterized by high photoelectric conversion efficiency(PCE),low cost and easy be prepared by solution process,perovskite solar cells(PSCs)have a unique advantage in the development of thin,lightweight and portable flexible solar cells,which can be used in wearable devices,photovoltaic buildings and other fields.At present,due to the challenge of depositing uniform and high-quality perovskite films on flexible substrates,the PCE of single juction flexible perovskite solar cells has reached 24.08%,but still lags behind rigid perovskite solar cells(certified PCE is 26.1%).Moreover,the inevitable generation of grain boundary cracks in flexible perovskite films during preparation and bending cycles poses a great challenge to the stability and reliability of flexible perovskite solar cells.The research progress in improving the PCE and stability of flexible perovskite solar cells is systematically reviewed and summarized from different perspectives,such as flexible substrate,grain modulation,grain boundary enhancement,interfacial passivation and structural optimization.Finally,the problems and challenges for the future development of flexible perovskite solar cells are prospected.

关 键 词：柔性 钙钛矿太阳电池(PSC) 高效率 稳定性 晶粒 晶界 界面 

分 类 号：TM914.4[电气工程—电力电子与电力传动]