微生物燃料电池耦合光催化技术降解葡萄酒清洗废水研究  

Study on Degradation of Wine Production Wastewater by Microbial Fuel Cell Coupled Photocatalytic Technology

作　　者：张秀丽 王延明 李春虎[2] ZHANG Xiu-li;WANG Yan-ming;LI Chun-hu(Qingdao Engineering Vocational College,Qingdao Shandong 266111,China;Ocean University of China,Qingdao Shandong 266000,China)

机构地区：[1]青岛工程职业学院,山东青岛266111 [2]中国海洋大学,山东青岛264200

出　　处：《当代化工》2024年第1期63-67,72,共6页Contemporary Chemical Industry

基　　金：青岛市民生科技计划项目(项目编号:17-3-3-71-nsh);2020年山东省教育教学研究课题(项目编号:2020JXQ029);青岛市社会科学规划项目(项目编号:QDSKL2201347、QDSKL2201346)。

摘　　要：光催化耦合微生物降解技术,在微生物代谢后期,污水中COD下降到光催化剂反应的范围,利用光能激发催化反应,将有机物质氧化成活性基团,可以将水体中难降解的有机物分解。以碳棒作为阳极,以碳布材料作为阴极,以负载TiO_(2)的活性炭作为生物载体,构建微生物燃料电池体系。葡萄酒废水酸性环境下微生物的生长缓慢,当阳极底物质量浓度由1000 mg·L^(-1)增大到3000 mg·L^(-1)时,COD去除率由较低水平的67%增大到较高水平的92%。在一定范围内,随着阳极底物质量浓度的增加,COD的去除率也有所增加。当阳极底物质量浓度由3000 mg·L^(-1)增大到4500 m·L^(-1)时,COD去除率由92%减小到81%,光催化的引入对处理低浓度的氨氮、总磷和COD效果均高于90%。During using photocatalytic coupling microbial degradation technology,in the late stage of microbial metabolism,COD in sewage is reduced to the range of photocatalytic reaction,and light energy is used to stimulate catalytic reaction to oxidize organic substances into active groups,which can decompose refractory organic substances in water.A microbial fuel cell system was constructed by using carbon rods as anodes,carbon cloth materials as cathodes,and activated carbon loaded with TiO_(2) as biological carriers.The growth of microorganisms in the acidic environment of wine wastewater was slow.When the mass concentration of anode substrate increased from1 000 mg·L^(-1) to 3 000 mg·L^(-1),the COD removal rate increased from 67%to 92%.The mass concentration of anode substrate increased to a certain extent,and the removal rate of COD in the anode chamber of MFC increased accordingly.When the anode substrate mass concentration was increased from 3 000 mg·L^(-1) to 4 500 m·L^(-1),the COD removal rate decreased from 92%to 81%.The removal rates of ammonia nitrogen,total phosphorus and COD under low concentrations were more than 90%after the introduction of photocatalysis.

关 键 词：COD降解 生物催化反应 输出电压 光催化活性 

分 类 号：X703.1[环境科学与工程—环境工程]