非金属催化剂在环氧化物和环状酸酐共聚中的研究进展  

Advances in metal-free catalysts in copolymerization of epoxides and cyclic anhydrides

作　　者：张强 王宪飞 王凯[1] 骆广生[1] 路忠凯 ZHANG Qiang;WANG Xianfei;WANG Kai;LUO Guangsheng;LU Zhongkai(State Key Laboratory of Chemical Engineering,Department of Chemical Engineering,Tsinghua University,Beijing 100084,China;Sinochem Energy Company Limited,Beijing 100031,China;Zhenghe Group Company Limited,Dongying 257399,Shandong,China)

机构地区：[1]清华大学化学工程系,化学工程联合国家重点实验室,北京100084 [2]中化能源股份有限公司,北京100031 [3]正和集团股份有限公司,山东东营257399

出　　处：《化工学报》2024年第1期60-73,共14页CIESC Journal

基　　金：国家自然科学基金项目(21991104)。

摘　　要：环氧化物与环状酸酐的开环共聚是一种新型的脂肪族聚酯合成技术,其技术核心之一是催化剂的选择与应用。与金属催化剂相比,非金属催化剂在简易性、低毒性、单体适应性、经济性等方面表现出潜在优势,得到迅速发展。针对非金属催化剂在环氧化物和环状酸酐共聚领域的研究进展进行了综述,总结并评述了近年来有机碱、Lewis酸碱对以及其他非金属催化剂在开环共聚反应中的工作机制认识和催化实施效果,对其发展方向和工业化应用潜力进行了展望。The ring-opening copolymerization of epoxides and cyclic anhydrides is a new type of aliphatic polyester synthesis technology.One of its core technologies is the selection and application of catalysts.Metal-free catalysts exhibit potential advantages compared to metal catalysts with respect to simplicity,low toxicity,monomer adaptability and economy,and have developed rapidly.This article reviews the research progress of metal-free catalysts in the copolymerization of epoxides and cyclic anhydrides,which summarizes the understanding of the working mechanisms and catalytic implementation effects of organic bases,Lewis acid-base pairs,and other metalfree catalysts in the ring-opening copolymerization recently,and proposes prospects for the development direction and industrial application potential of the catalyst.

关 键 词：非金属催化剂 环氧化物 环状酸酐 共聚 

分 类 号：TQ032.4[化学工程]