氢燃料电池汽车用氢气中痕量硫化物的分析进展  

Progress in the analysis of trace sulfides in hydrogen for hydrogen fuel cell vehicles

作　　者：成春喜 王目周[3,5] 申友军 雷军 Cheng Chun-xi;Wang Mu;Zhou Shen-you;Lei Jun(Hubei Industrial Gas Purification and Utilization Key Laboratory,Wuhan,Hubei 430074,China;Haiso Technology limited company,Wuhan,Hubei 430074,China;National Engineering Research Center of Coal Gasification and Coal-Based Advanced Materials,Jinan,Shangdong 250000,China;YanKuang LuNan Chemicals Co.,Ltd,Zaozhuang,Shangdong 277000,China;ShanDong Energy Group Co.,Ltd,Jinan,ShanDong 250000,China)

机构地区：[1]工业气体净化精制与利用湖北省重点实验室,湖北武汉430074 [2]华烁科技股份有限公司,湖北武汉430074 [3]大型煤气化及煤基新材料国家工程研究中心,山东济南250000 [4]兖矿鲁南化工有限公司,山东枣庄277000 [5]山东能源集团有限公司,山东济南250000

出　　处：《福建分析测试》2024年第1期15-21,共7页Fujian Analysis & Testing

基　　金：山东省重点研发计划(重大科技创新工程)项目(2020CXG010402)。

摘　　要：氢燃料电池汽车(FCV)用氢气中的痕量硫化物会导致催化剂中毒,使电池的性能显著下降。各标准组织均对氢燃料电池用氢气中的硫含量做了严格的限值,要求硫化物的含量(以H_(2)S或S_(1)计)低于0.004μmol/mol,这对硫化物的分析提出了很高的要求。本文介绍了气体分析领域中各种痕量硫分析的方法和原理,比较了它们的优缺点,并对它们在FCV用氢中痕量硫分析的应用进行了探讨。Trace sulfides in hydrogen for hydrogen fuel cell vehicles(FCV)can cause catalyst poisoning,significantly degrading battery performance.All standard organizations have made strict limits on the sulfur content in hydrogen for hydrogen fuel cells,requiring the sulfide content(in terms of H_(2)S or S_(1))to be less than 0.004μmol/mol,which puts forward high requirements for the analysis of sulfides.In this paper,the methods and principles of trace sulfur analysis in the field of gas analysis are introduced,their advantages and disadvantages are compared,and their application in trace sulfur analysis in FCVhydrogen is discussed.

关 键 词：氢燃料电池汽车 氢气 痕量硫化物 

分 类 号：O659.2[理学—分析化学]