低表面能环氧树脂超疏水涂层的制备与研究  

Preparation and study of low surface energy epoxy resin superhydrophobic coatings

作　　者：刘华 常昌凡 刘坐镇 LIU Hua;CHANG Chang-fan;LIU Zuo-zhen(Sino Polymer Co.,Ltd.,of ECUST,Shanghai Engineering Research Center of New Anticorrosion Material,Shanghai 200237,China;College of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China)

机构地区：[1]华东理工大学华昌聚合物有限公司,上海防腐蚀新材料工程技术研究中心,上海200237 [2]华东理工大学材料科学与工程学院,上海每200237

出　　处：《热固性树脂》2024年第1期25-30,共6页Thermosetting Resin

基　　金：国家重点研发计划项目(2022YFB3709201);上海市科技计划项目(20511107302)。

摘　　要：制备工艺复杂、表面粗糙结构耐久性差等因素制约了超疏水涂层在现实中的大规模应用。本研究采用十八烷酸对环己二胺四官能团环氧树脂(AG602)接枝改性制备了低表面能环氧树脂SAEP,并将SAEP与疏水纳米二氧化硅粒子共混后涂膜,对其热固化后涂层的性能进行研究。结果表明:当nmSiO_(2)质量分数为30%时,涂层表面具备超疏水性,水接触角为156.5°,滚动角为5.1°。涂层在承受砂纸45次循环打磨后仍能保持超疏水性。此外,涂层还具备优良的自清洁能力与耐酸碱腐蚀能力。The complex preparation process and poor durability of surface roughness structure restrict the large-scale application of superhydrophobic coatings in reality.In this study,a low surface energy epoxy resin SAEP was prepared by grafting octadecanoic acid onto cyclohexanediamine tetrafunctional epoxy resin(AG602).The SAEP was mixed with hydrophobic nano silica particles and coated.The properties of the coating after thermal curing were investigated.The results showed that when the nmSiO_(2) content was 30 wt%,the coating surface exhibited superhydrophobicity,with a water contact angle of 156.5°and a rolling angle of 5.1°.The coating could still maintain superhydrophobicity after being subjected to 45 cycles of sandpaper polishing.In addition,the coating also had excellent self-cleaning ability and acid alkali corrosion resistance.

关 键 词：超疏水涂层 低表面能 环氧树脂 十八烷酸 纳米二氧化硅 自清洁 耐腐蚀 

分 类 号：TQ323.5[化学工程—合成树脂塑料工业]