Polarizable Additive with Intermediate Chelation Strength for Stable Aqueous Zinc‑Ion Batteries  

作　　者：Yuting Xia Rongao Tong Jingxi Zhang Mingjie Xu Gang Shao Hailong Wang Yanhao Dong Chang‑An Wang 

机构地区：[1]State Key Lab of New Ceramics and Fine Processing,School of Materials Science and Engineering,Tsinghua University,Beijing 100084,People’s Republic of China [2]School of Materials Science and Engineering,Zhengzhou University,Zhengzhou 450001,Henan,People’s Republic of China

出　　处：《Nano-Micro Letters》2024年第5期41-55,共15页纳微快报（英文版）

基　　金：This work is financially supported by National Natural Science Foundation of China(NSFC-No.52173257 and 52372064).

摘　　要：Aqueous zinc-ion batteries are promising due to inherent safety,low cost,low toxicity,and high volumetric capacity.However,issues of dendrites and side reactions between zinc metal anode and the electrolyte need to be solved for extended storage and cycle life.Here,we proposed that an electrolyte additive with an intermediate chelation strength of zinc ion—strong enough to exclude water molecules from the zinc metal-electrolyte interface and not too strong to cause a significant energy barrier for zinc ion dissociation—can benefit the electrochemical stability by suppressing hydrogen evolution reaction,overpotential growth,and den-drite formation.Penta-sodium diethylene-triaminepentaacetic acid salt was selected for such a purpose.It has a suitable chelating ability in aqueous solutions to adjust solvation sheath and can be readily polarized under electrical loading conditions to further improve the passivation.Zn||Zn symmetric cells can be stably operated over 3500 h at 1 mA cm^(-2).Zn||NH4V4O10 full cells with the additive show great cycling stability with 84.6%capacity retention after 500 cycles at 1 A g^(-1).Since the additive not only reduces H2 evolution and corrosion but also modifies Zn2+diffusion and deposition,highlyreversible Zn electrodes can be achieved as verified by the experimental results.Our work offers a practical approach to the logical design of reliable electrolytes for high-performance aqueous batteries.

关 键 词：Aqueous zinc-ion batteries Electrolyte additives DTPA-Na Chelation strength 

分 类 号：O646[理学—物理化学] TM912[理学—化学]