Integrating Levels of Hierarchical Organization in Porous Organic Molecular Materials  

作　　者：Jesus Ferrando‑Soria Antonio Fernandez 

机构地区：[1]Instituto de Ciencia Molecular(ICMol),Universidad de Valencia,46980 Valencia,Spain [2]School of Science,Loughborough University,Loughborough LE113TU,UK

出　　处：《Nano-Micro Letters》2024年第5期134-153,共20页纳微快报（英文版）

基　　金：the MICINN (Spain)(Projects PID2019-104778GB-I00, PID2020-115100GB-I00;Excellence Unit “Maria de Maeztu” CEX2019-000919-M);the Royal Society of Chemistry;funded by Generalitat Valenciana;(PROMETEU/2021/054 and SEJI/2020/034);the “Ramón y Cajal” program (RYC2019-027940-I);the Royal Society (RGSR1221390);Royal Society of Chemistry (R21-5119312833) for the funding.

摘　　要：Porous organic molecular materials(POMMs)are an emergent class of molecular-based materials characterized by the formation of extended porous frameworks,mainly held by non-covalent interactions.POMMs represent a variety of chemical families,such as hydrogen-bonded organic frameworks,porous organic salts,porous organic cages,C-H···πmicroporous crystals,supramolecular organic frameworks,π-organic frameworks,halogen-bonded organic framework,and intrinsically porous molecular materials.In some porous materials such as zeolites and metal organic frameworks,the integration of multiscale has been adopted to build materials with multifunctionality and optimized properties.Therefore,considering the significant role of hierarchy in porous materials and the growing importance of POMMs in the realm of synthetic porous materials,we consider it appropriate to dedicate for the first time a critical review covering both topics.Herein,we will provide a summary of literature examples showcasing hierarchical POMMs,with a focus on their main synthetic approaches,applications,and the advantages brought forth by introducing hierarchy.

关 键 词：Porous organic molecular materials HIERARCHY Hydrogen-bonded organic frameworks Porous cages FULLERENE 

分 类 号：TB383.4[一般工业技术—材料科学与工程]