Transient self-assembly driven by chemical fuels  

作　　者：Ling Wang Jin Yuan Jingcheng Hao 

机构地区：[1]Key Laboratory of Colloid and Interface Chemistry,Shandong University,Ministry of Education,Jinan 250100,China [2]School of Chemistry and Chemical Engineering,Qilu Normal University,Jinan 250200,China

出　　处：《ChemPhysMater》2024年第1期1-23,共23页化学物理材料（英文）

基　　金：the National Natural Science Foundation of China(Grant Nos.22032003 and 22072073).

摘　　要：Self-assembly has been extensively studied in chemistry,physics,biology,and materials engineering and has become an important“bottom-up”approach in creating intriguing structures for different applications.Using dissipative self-assembly to construct fuel-dependent,energy-consuming,and dynamic nonequilibrium systems is important for developing intelligent life-like materials.Furthermore,dissipative self-assembly has become a research hotspot in materials chemistry,biomedical science,environmental chemistry,and physical chemistry.An in-depth understanding of the process and mechanism provides useful insights to the researchers for devel-oping materials using dissipative self-assembly and also helps guide future innovation in material fabrication.This critical review comprehensively analyzes various chemical fuel input and energy consumption mechanisms,supported by numerous illustrative examples.Versatile transient assemblies,including gels,vesicles,micelles,and nanoparticle aggregates,have been systematically studied in our and other laboratories.The relationship between the molecular structure of precursors and temporal assemblies in dissipative self-assemblies is discussed from the perspective of physical chemistry.Using dissipative self-assembly methods to construct functional assemblies provides important implications for constructing high-energy,nonequilibrium,and intelligent functional materials.

关 键 词：SELF-ASSEMBLY Chemical Fuel Consumption mechanisms Functional assemblies 

分 类 号：O64[理学—物理化学]