微反应器在含能材料合成中的应用及展望  

Review on the Application of Microreactor in the Synthesis Processes of Energetic Materials

作　　者：周琳 杨炜[2] 吕阳成[1] ZHOU Lin;YANG Wei;LÜYang-cheng(State Key Laboratory of Chemical Engineering,Department of Chemical Engineering,Tsinghua University,Beijing 100084,China;Institute of Chemical Materials,China Academy of Engineering Physics,Mianyang 621999,China)

机构地区：[1]清华大学化工系化学工程联合国家重点实验室,北京100084 [2]中国工程物理研究院化工材料研究所,四川绵阳621999

出　　处：《含能材料》2024年第3期325-344,共20页Chinese Journal of Energetic Materials

基　　金：国家自然科学基金(21422603,U1662120,21978152)。

摘　　要：目前传统的间歇制备过程由于受制于宏观尺度难以对工艺参数、产物结构及性能实现精准调控,导致产物的均一性差,制备过程存在显著的安全隐患。因此,如何实现含能材料的安全、可控和高效的制备已成为目前研究的热点。微反应器以其微型化、集成化、高度安全性和出色的传质传热效率等诸多优势,高度契合含能材料制备过程的需求。因此,微反应器技术逐渐引起了研究者的广泛关注,在含能材料制备中崭露头角。本文介绍了微反应器在危险化工合成过程及含能材料制备中应用的国内外研究进展,特别关注了其在单质含能材料和复合含能材料制备中的潜在应用,对未来的研究方向进行了展望,强调了未来微反应器技术领域的发展需求包括规模化生产、三废处理及智能化平台建设等。Nowadays,the conventional batch preparation process is difficult to achieve accurate control of process parameters,product structure and properties due to the macro scale,resulting in poor product uniformity and significant safety risk in the preparation process.Therefore,how to achieve safe,controllable,and efficient preparation of energetic materials has become a popular research topic.Microreactors are well⁃suited for preparing energetic materials due to their advantages of miniaturization,integration,high safety,and excellent mass and heat transfer efficiencies.Consequently,microreactor technology has gradually attracted the wide attention of researchers and emerged in the preparation of energetic materials..This paper provides a detailed overview of the domestic and international research progress on the application of microreactors in hazardous chemical synthesis processes and the preparation of energetic materials.Special attention is given to the potential application of microreactors in the preparation of monolithic and composite energetic materials.The future research direction was prospected,and the future devel⁃opment needs of microreactor technology were emphasized,including large⁃scale production,three wastes treatment and intelli⁃gent platform construction.

关 键 词：微反应器 微流控技术 含能材料 强放热反应 过程强化 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] O69[理学—化学]