膨胀型钢结构防火涂料的研究进展  

Research Progress on the Intumescent Fire Retardant Coatings for Steel Structure

作　　者：吴沛沛 张依晴 田爱琴 曹鑫 张玲 王锦 张冬海[3] Wu Peipei;Zhang Yiqing;Tian Aiqin;Cao Xin;Zhang Ling;Wang Jin;Zhang Donghai(National Engineering Research Center for High-Speed EMU,China Railway Rolling Stock(CRRC)QingdaoSi Fang Co.,Ltd.,Qingdao,Shandong 266111,China;Beijing Key Laboratory for Science and Application ofFunctional Molecular and Crystalline Materials,Department of Chemistry and Chemical Engineering,Universityof Science and Technology Beijing,Beijing 100083,China;State Key Laboratory of Mesoscience andEngineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100190,China;Shanghai Pengtu Antibacterial New Materials Co.,Ltd.,Shanghai 201800,China)

机构地区：[1]中车青岛四方机车车辆股份有限公司国家工程研究中心,山东青岛266111 [2]北京科技大学化学与生物工程学院化学与化学工程系,北京100083 [3]中国科学院过程工程研究所多相复杂系统国家重点实验室,北京100190 [4]上海鹏图抗菌新材料有限公司,上海201800

出　　处：《涂料工业》2024年第3期59-65,共7页Paint & Coatings Industry

摘　　要：以P-C-N(聚磷酸铵APP、季戊四醇PER、三聚氰胺MEL组成)为膨胀体系的钢结构防火涂料应用广泛,但普遍存在耐水性差、防火抑烟效果达不到预期等问题。以P-C-N膨胀体系的优化及发展为主线,梳理和总结了膨胀型钢结构防火涂料相关研究。发现通过对膨胀体系中亲水性组分的改性来优化P-C-N膨胀体系、在防火涂料中添加碳材料、过渡金属化合物等填料,可协同提高防火涂料性能并取得了较好的效果。然而,这些研究仍未能很好地解决防火涂料环境耐久性及高效防火的发展要求,因此开发新的膨胀体系已成为当前研究的需求与热点。Fire retardant coatings for steel structure with P-C-N(composed of ammonium polyphosphate APP,pentaerythritol PER,and melamine MEL)as the expansion system are widely used,but there are common problems such as poor water resistance and unsatisfactory fire and smoke suppression effects.This article took the optimization and development of P-C-N intumescent system as the main line,and sorted out and summarized the relevant research on intumescent fire retardant coatings for steel structure.It was found that optimizing the P-C-N expansion system through hydrophilic components and adding fillers such as carbon materials and transition metal compounds to the fire retardant coatings had achieved good results in synergistically improving the performance of the fire retardant coatings.However,the fire retardant coatings still could not be solved well.With the development requirements of environmental durability and efficient fire protection,the development of new expansion systems had become a current research hotspot.

关 键 词：钢结构 防火涂料 膨胀体系 研究进展 

分 类 号：TQ637.6[化学工程—精细化工]