Fully Conjugated Covalent Organic Frameworks:Synthesis,Structures and Applications  

作　　者：Yueshuai Xu Guanshi Ren Dianqi Zhang Lishui Sun Yingjie Zhao 

机构地区：[1]College of Polymer Science and Engineering,Qingdao University of Science and Technology,Qingdao,Shandong,266000 China

出　　处：《Chinese Journal of Chemistry》2023年第23期3447-3472,共26页中国化学（英文版）

基　　金：supported by the National Natural Science Foundation of China(22175101,51972185);the Natural Science Foundation of Shandong Province(ZZR2020ZD38).

摘　　要：This review presents a comprehensive examination of fully conjugated covalent organic frameworks(COFs),which constitute an emerging class of porous materials with immense potential for diverse applications.This article focuses on diversified fully conjugated COFs,including sp2 carbon-carbon linkages,pyrazine linkages,benzobisoxazole linkages,dioxin linkages,β-aminoalkenone linkages,etc.The synthesis techniques and structural attributes of these COFs are expounded upon in great detail,along with their potential applications in various fields.The review thus provides a valuable resource for researchers keen on delving into the synthesis and applications of fully conjugated COFs,thereby highlighting their potential for developing novel functional materials with distinctive properties.

关 键 词：Covalent organic frameworks Fully-conjugated system CRYSTALLINITY STABILITY CONJUGATION Porous polymers Conjugated polymers 

分 类 号：O62[理学—有机化学]