基于三嗪环结构的高固体份羟基树脂的制备与表征  

Synthesis and characterization of high-solidpolyols based on thiotriazinone structure

作　　者：陈之善 马晓阳 黎家强 汤汉良 CHEN Zhi-shan;MA Xiao-yang;LI Jia-qiang;TANG Han-liang(Qingyuan Hi-tech Huayuan Institute of Science and Technology Collaborative Innovation Co.,Ltd.,Qingyuan 511517,China)

机构地区：[1]清远高新华园科技协同创新研究院有限公司,广东清远511517

出　　处：《应用化工》2022年第S01期110-112,117,共4页Applied Chemical Industry

基　　金：广东省清远市科技计划项目(200525114561217)。

摘　　要：针对高固体份聚氨酯涂料存在的干燥速度慢、最终硬度低的问题,创新性地采用含有三嗪环结构的异氰尿酸三缩水甘油酯(TGIC)与一元酸进行开环反应,制备了固体份80%、低粘度的羟基树脂。经测试,采用该类树脂制备的聚氨酯涂料具有挥发性有机化合物(VOC)含量低、干燥速度快、最终硬度高等优势,可广泛应用于汽车、轨道列车、风电叶片、工业设备等领域的涂装。The ring opening reaction of 1,3,5-triglycidyl isocyanurate(TGIC)containing thiotriazinone structure and monobasic acid is applied to improve the drying speed and hardness of high-solid polyurethane coatings.Hydroxyl resins with 80%solid content and low viscosity are obtained.Polyurethane coatings made by these hydroxyl resins show low VOC content,fast drying speed and high final hardness,which could be used in the coating of automobile,rail train,wind blade,industrial equipment etal.

关 键 词：三嗪环 高固体份 羟基树脂 

分 类 号：TQ322[化学工程—合成树脂塑料工业] TQ430TQ630