PNIMMO与典型固体推进剂组分表界面作用研究  

Study on surface/interface actions of PNIMMO with typical solid propellant components

作　　者：郑瑞雪 刘红妮[2] 周文静[2] 鄂秀天凤 莫洪昌[2] 朱勇[2] 孟子晖[1] ZHENG Ruixue;LIU Hongni;ZHOU Wenjing;E Xiutianfeng;MO Hongchang;ZHU Yong;MENG Zihui(Beijing Institute of Technology,Beijing 100081,China;Xi’an Modern Chemistry Research Institute,Xi’an 710065,China)

机构地区：[1]北京理工大学,北京100081 [2]西安近代化学研究所,西安710065

出　　处：《兵器装备工程学报》2024年第1期230-234,共5页Journal of Ordnance Equipment Engineering

摘　　要：为实现聚3-硝酸酯甲基-3-甲基氧杂环丁烷(PNIMMO)在推进剂配方中的进一步应用,研究了PNIMMO与4种典型固体推进剂组分(RDX、HMX、AP及Al)之间的表界面作用。利用接触角测量仪测定了各组分与不同溶剂的接触角,进而得到了各组分的表面张力,在此基础上计算了PNIMMO与典型固体推进剂组分的界面张力和黏附功,并推测了其作用机理。结果表明:PNIMMO的表面张力较小,易于在推进剂组分表面铺展。PNIMMO与推进剂组分间的界面张力大小顺序为:γ_(SL)(PNIMMO-AP)>γ_(SL)(PNIMMO-Al)>γ_(SL)(PNIMMO-RDX)>γ_(SL)(PNIMMO-HMX)。PNIMMO与推进剂组分间的黏附功大小顺序为:W_(a)(PNIMMO-AP)>W_(a)(PNIMMO-RDX)>W_(a)(PNIMMO-HMX)>W_(a)(PNIMMO-Al)。PNIMMO与HMX粘结作用最强,与Al粘结作用最弱。与传统粘合剂HTPB相比,PNIMMO有利于改善推进剂的力学性能和流变性能。For further application of poly(3-nitratomethy-l-3-methyl oxetane)(PNIMMO)in propellant formulations,the surface-interface action between PNIMMO and four typical solid propellant components(RDX,HMX,AP and Al)was investigated.The contact angles of each component with different solvents were tested by contact angle measuring instrument,and the surface tension was obtained.Then the interfacial tension and the adhesive work were calculated,and the mechanism was speculated.As a result,PNIMMO has a low surface tension and can spread easily on the surface of propellant components.The contrast of interfacial tension between PNIMMO and the propellant components is:γ_(SL)(PNIMMO-AP)>γ_(SL)(PNIMMO-Al)>γ_(SL)(PNIMMO-RDX)>γ_(SL)(PNIMMO-HMX).The contrast of adhesive work between PNIMMO and solid propellant components is:W_(a)(PNIMMO-AP)>W_(a)(PNIMMO-RDX)>W_(a)(PNIMMO-HMX)>W_(a)(PNIMMO-Al).And PNIMMO has the strongest bonding effect with HMX,while has the weakest bonding effect with Al.Compared with HTPB,PNIMMO is beneficial to improve the mechanical properties and rheological properties of propellants.

关 键 词：物理化学 PNIMMO 推进剂组分 表界面 粘结作用 

分 类 号：TQ-430.1[化学工程]