难熔金属及金属碳/氧化物粉体制备技术研究进展  

Research progress on refractory metal and metallic carbide/oxide powder preparation techniques

作　　者：魏玉鹏[1,2,3,4] 陈珊 王雅婷 王东新 于艳红 张萌 肖荣振 朱亮[1,2] 程越伟[3,4] WEI Yupeng;CHEN Shan;WANG Yating;WANG Dongxin;YU Yanhong;ZHANG Meng;XIAO Rongzhen;ZHU Liang;CHENG Yuewei(School of Materials Science and Engineering,Lanzhou University of Technology,Lanzhou 730050,China;State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals,Lanzhou University of Technology,Lanzhou 730050,China;Northwest Rare Metal Materials Research Institute Ningxia Co.,Ltd,Shizuishan 753000,China;State Key Laboratory of Special Rare Metal Materials,Shizuishan 753000,China)

机构地区：[1]兰州理工大学材料科学与工程学院,兰州730050 [2]兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室,兰州730050 [3]西北稀有金属材料研究院宁夏有限公司,石嘴山753000 [4]稀有金属特种材料国家重点实验室,石嘴山753000

出　　处：《航空学报》2024年第3期46-60,共15页Acta Aeronautica et Astronautica Sinica

基　　金：国家自然科学基金(52262012);甘肃省教育厅创新基金(2021A-030);甘肃省优秀研究生创新之星项目(2022CXZX-400,2023CXZX-398);西北稀有金属材料研究院宁夏有限公司稀有金属特种材料国家重点实验室开放课题基金(SKL2021K001)。

摘　　要：难熔金属及金属碳/氧化物具有高熔点、高温稳定性、强耐腐蚀性等优异特性,在燃气叶片、电子管、火箭引擎、切削刀具、高温热元件、涡轮喷嘴等高温高压、强腐蚀性等环境下被广泛应用。本文介绍了难熔金属及金属碳/氧化物粉体的应用,梳理了难熔金属及金属碳/氧化物粉体的机械法、还原法、燃烧法、溶胶-凝胶法、水热法、微波法、沉淀法、热解法、爆炸法和等离子体法等制备工艺,并比较各种工艺在制备难熔金属及金属碳/氧化物粉体过程中的优缺点;重点评述难熔金属及金属碳/氧化物Mo、W、Ta、WC、ZrC、TiC、CeO_(2)、ZrO_(2)、Y_(2)O_(3)等粉体的研究现状,并展望了难熔粉体的发展方向,为难熔粉体的制备工艺和应用提供参考。Having such excellent properties as high melting point,high temperature stability,and strong corrosion re⁃sistance,refractory metals,metallic carbides and metallic oxides.These are widely used in high-temperature and highpressure,strong corrosion and other environments such as gas blades,electronic tubes,rocket engines,cutting tools,high temperature thermal components,and turbine nozzles.Focusing on the preparation methods of refractory metals and metallic carbides/oxides powder,including the mechanical method,reduction method,combustion method,sol-gel method,hydrothermal method,microwave method,precipitation method,pyrolysis method,explo⁃sion method and plasma method,this paper analyzed the advantages,disadvantages and status of preparation meth⁃ods such as Mo,W,Ta,WC,ZrC,TiC,CeO_(2),ZrO_(2) and Y_(2)O_(3),and prospected the development status of the prepa⁃ration of refractory powder based on electric explosion method to provide reference for the preparation and application of refractory powders.

关 键 词：难熔金属 难熔粉体金属碳化物粉体 金属氧化物粉体 制备方法 

分 类 号：V19[航空宇航科学与技术—人机与环境工程] TB35[一般工业技术—材料科学与工程]