南宋和元代龙泉窑粉青瓷釉色比较研究  

Comparative Study on the Glaze Color of Longquan Light Greenish-blue Celadon in the Southern Song and Yuan Dynasties

作　　者：桑振[1] 靳文文 王学武 吴明俊 沈子珍 付向阳[1] 袁小娟[1] 郝亚荣 SANG Zhen;JIN Wen-wen;WANG Xue-wu;WU Ming-jun;SHEN Zi-zhen;FU Xiang-yang;YUAN Xiao-juan;HAO Ya-rong(Shaanxi University of Science&Technology,Xi’an 710021,China;Xi’an Chai Kiln Cultural Museum,Xi’an 710021,China;Longquan Celadon Museum,Longquan 331181,China)

机构地区：[1]陕西科技大学,西安710021 [2]西安柴窑文化博物馆,西安710021 [3]龙泉青瓷博物馆,龙泉331181

出　　处：《中国陶瓷》2024年第3期66-73,共8页China Ceramics

基　　金：陕西省重点科技项目基金“耀州窑、汝窑之于柴窑脉络关系比较研究”(2022GY-340)。

摘　　要：为了研究南宋与元代龙泉粉青瓷釉呈色机理,采用colorimeter,XRF,XRD,Raman spectrometer,XPS等对南宋和元代龙泉粉青瓷釉进行对比分析。结果表明,南宋粉青瓷L*值大于元代,而a*、b*值小于元代粉青瓷。南宋粉青瓷的烧成温度低于元代。龙泉粉青瓷乳浊如玉的质感主要是受釉层内小而密集气泡与大量石英晶体对光的影响所致。Fe2O3的化学色主导了龙泉青瓷的呈色,且南宋粉青瓷的Fe2+与Fe3+的比值高于元代粉青瓷,是南宋粉青瓷偏蓝而元代粉青瓷偏绿的主要原因。In order to study the coloring mechanism of Longquan light greenish-blue celadon glaze during the Southern Song and Yuan dynasties,a comparative analysis was conducted using colorimeter,XRF,XRD,Raman spectrometer,and XPS.The results show that the L*value of Southern Song Dynasty light greenish-blue celadon is larger than that from the Yuan Dynasty,while the values of a*and b*are smaller than those from the Yuan Dynasty light greenish-blue celadon.The firing temperature of the Southern Song Dynasty celadon is lower than that of the Yuan Dynasty.The opaque and jade-like appearance of the Longquan celadon is mainly caused by the influence of small and dense bubbles and a large number of quartz crystals in the glaze layer.The chemical color of Fe2O3 dominates the color of Longquan celadon,and the ratio of Fe2+to Fe3+in Southern Song Dynasty light greenish-blue celadon is higher than that of Yuan Dynasty light greenish-blue celadon.This is the main reason why Southern Song Dynasty light greenish-blue celadon is bluish and Yuan Dynasty light greenish-blue celadon is greenish.

关 键 词：龙泉青瓷 粉青 南宋 元代 釉色 

分 类 号：TQ174.43[化学工程—陶瓷工业]