RFCC分子筛催化剂的失活机理及抗失活方法研究进展  

Research Progress of Deactivation Mechanism and Anti Deactivation Methods of RFCC Molecular Sieve Catalysts

作　　者：周小钰 么秋香 孙鸣[2] 谢雨欣 杨志凡 Zhou Xiaoyu;Yao Qiuxiang;Sun Ming;Xie Yuxin;Yang Zhifan(Xijing University,Xian Key Laboratory of Advanced Photo-electronics Materials and Energy Conversion Device,Xi'an 710123,China;School of Chemical Engineering,Northwest University,Chemical Engineering Research Center of the Ministry of Education for Advanced Use Technology of Shanbei Energy,Xi'an 710069,China)

机构地区：[1]西京学院,西安市先进光电子材料与能源转换器件重点实验室,陕西西安710123 [2]西北大学化工学院,陕北能源先进化工利用技术教育部工程研究中心,陕西西安710069

出　　处：《广东化工》2024年第4期55-57,共3页Guangdong Chemical Industry

基　　金：国家自然科学基金面上项目(22278338);国家级“大学生创新创业训练计划”(X202312715010);西京学院特区人才专项基金(XJ23T02)。

摘　　要：催化裂化是石油化工中最重要的炼油工艺之一,其中高活性沸石催化剂是重油催化裂化的关键。但重油的复杂组成和恶劣的反应环境使沸石催化剂易失活,不利于重油转化和产品质量提升。本文综述了沸石催化剂在重油催化裂化过程中的失活机理,阐明了其抗失活方法,如金属负载改性、结构调控、尺寸调控及添加剂使用等。Catalytic cracking is one of the most important refining processes in petrochemical industry.The highly active zeolite catalyst is the key to heavy oil catalytic cracking.However,the complex composition of heavy oil and the harsh reaction environment make zeolite catalysts prone to deactivation,which is not conducive to heavy oil conversion and product quality improvement.This article reviews the deactivation mechanism of zeolite catalysts in heavy oil catalytic cracking process,and elucidates the anti deactivation methods of molecular sieve catalysts,such as metal loading modification,structural regulation,size regulation,and additive use.

关 键 词：重油 催化裂化 沸石分子筛 失活 

分 类 号：TQ524[化学工程—煤化学工程]