水性聚氨酯海洋防污涂层构建及控释机理研究  

Controlled Release Mechanism of Waterborne Polyurethane Marine Antifouling Coating

作　　者：张初镱 肖巧艺 谢志鹏[1] 黄从树[1] 邓冰锋[1] 王晶晶[1] 史治国 易杰 Zhang Chuyi;Xiao Qiaoyi;Xie Zhipeng;Huang Congshu;Deng Bingfeng;Wang Jingjing;Shi Zhiguo;Yi Jie(Luoyang Ship Material Research Institute(LSMRI),State Key Laboratory for Marine Corrosion and Protection,Xiamen,Fujian 361100,China;College of Material and Textile Engineering,Jiaxing University,Jiaxing,Zhejiang 314001,China)

机构地区：[1]中国船舶重工集团公司第七二五研究所,海洋腐蚀与防护重点实验室,福建厦门361100 [2]嘉兴大学材料与纺织工程学院,浙江嘉兴314001

出　　处：《涂层与防护》2024年第3期6-6,7-11,共6页Coating and Protection

基　　金：国家自然科学基金青年项目(52101385);嘉兴市青年科技人才专项(2023AY40018)。

摘　　要：针对海洋防污涂料的环保要求,通过调控聚己内酯及聚四亚甲基醚二醇的用量,合成一系列可降解水性聚氨酯。水性聚氨酯薄膜吸水率及降解率随着聚己内酯链段用量增加而增加,其降解速率随温度增加而增加。水性聚氨酯海洋防污涂层的DCOIT释放速率与其降解速率正相关,可以通过调控WPU-PCLX的降解速率,从而控制WPU-PCLX海洋防污涂层的DCOIT释放速率。In order to meet the environmental requirements for marine antifouling coatings,a series of biodegradable waterborne polyurethanes were synthesized by controlling the amounts of polycaprolactone and polytetramethylene ether glycol.The water absorption and degradation rates of the waterborne polyurethane films increased with an increase in the polycaprolactone segment dosage.Furthermore,the degradation rate of the water-based polyurethane increased with temperature.The release rates of DCOIT in the waterborne polyurethane marine antifouling coatings were positively correlated with its degradation rate.Therefore,by regulating the degradation rate of WPU-PCLX,the release rate of DCOIT in the WPU-PCLX marine antifouling coatings can be controlled.

关 键 词：聚己内酯 水性聚氨酯 海洋防污 控释 

分 类 号：TQ630.7[化学工程—精细化工]