A review on ultra-small undoped MoS_(2) as advanced catalysts for renewable fuel production  

作　　者：Guoping Liu Lingling Ding Yuxuan Meng Ahmad Ali Guifu Zuo Xianguang Meng Kun Chang Oi Lun Li Jinhua Ye 

机构地区：[1]Hebei Provincial Laboratory of Inorganic Nonmetallic Materials,College of Materials Science and Engineering,North China University of Science and Technology,Tangshan,China [2]College of Materials Science and Technology,Nanjing University of Aeronautics and Astronautics,Nanjing,China [3]School of Materials Science and Engineering,Pusan National University,Busan,Korea [4]International Center for Materials Nanoarchitectonics(WPIMANA),National Institute for Materials Science(NIMS)1-1 Namiki,Tsukuba,Ibaraki,Japan

出　　处：《Carbon Energy》2024年第2期92-112,共21页碳能源（英文）

基　　金：support from the Tangshan Talent Funding Project(A202202007);the National Natural Science Foundation of China(21703065);the Natural Science Foundation of Hebei Province(B2018209267,E2022209039);the Basic Science Center Program for Ordered Energy Conversion of the National Natural Science Foundation of China(51888103).

摘　　要：Molybdenum disulfide(MoS_(2))has garnered significant attention in the field of catalysis due to the high density of active sites in its unique two-dimensional(2D)structure,which could be developed into numerous high-performance catalysts.The synthesis of ultra-small MoS2 particles(<10 nm)is highly desired in various experimental studies.The ultra-small structure could often lead to a distinct S-Mo coordination state and nonstoichiometric composition in MoSx,minimizing in-plane active sites of the 2D structure and making it probable to regulate the atomic and electronic structure of its intrinsic active sites on a large extent,especially in MoSx clusters.This article summarizes the recent progress of catalysis over ultra-small undoped MoS_(2) particles for renewable fuel production.Through a systematic review of their synthesis,structural,and spectral characteristics,as well as the relationship between their catalytic performance and inherent defects,we aim to provide insights into catalysis over this matrix that may potentially enable advancement in the development of high-performance MoS_(2)-based catalysts for sustainable energy generation in the future.

关 键 词：applications CATALYTIC MoS_(2) structure synthesis 

分 类 号：TQ426[化学工程]