Recent advances in transition-metal catalyzed nitrene transfer reactions with carbamates  

作　　者：Yanshu Luo Xinyu Zhang Yuanzhi Xia 

机构地区：[1]College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325035,China

出　　处：《Chinese Chemical Letters》2024年第3期76-86,共11页中国化学快报（英文版）

基　　金：the financial support provided by the National Natural Science Foundation of China(Nos.21572163 and 21873074);the Wenzhou Science&Technology Bureau(No.G20210032)。

摘　　要：Nitrene transfer reactions are powerful tools in synthetic organic chemistry.In recent years,transitionmetal catalyzed nitrene transfer reactions with carbamates as the nitrene precursors have been widely pursued.Such species undergoes facile C-H amination,aziridination,and bifunctionalization of alkenes under the catalysis of different transition metals including Rh,Fe,Ru and others,enabling the efficient construction of various nitrogen-containing molecules.In this review,the recent developments in nitrene transfer reactions with carbamates via N-O bond cleavage were introduced based on different types of reaction,and the key mechanistic information and synthetic applications of the methodologies were discussed.

关 键 词：Transition-metal catalysis Nitrene transfer CARBAMATE C—H amination AZIRIDINATION Bifunctionalization 

分 类 号：O621.251[理学—有机化学]