Advances in electrocarboxylation reactions with CO_(2)  

作　　者：Junjun Mao Yubo Wang Bo Zhang Yang Lou Chengsi Pan Yongf Zhu Ying Zhang 

机构地区：[1]Key Laboratory of Synthetic and Biological Colloids Ministry of Education,School of Chemical and Material Engineering,Jiangnan University,Wuxi,Jiangsu 214122,China [2]School of Physics,Peking University,Beijing 100091,China [3]Department of Chemistry,Tsinghua University,Beijing 100084,China

出　　处：《Green Carbon》2024年第1期45-56,共12页绿碳（英文）

基　　金：supported by the National Natural Science Foundation of China(22379054)and start-up funding from Jiangnan University.

摘　　要：Recently,significant research has been conducted on the conversion of carbon dioxide(CO_(2))into value-added chemicals.With the decreasing cost of clean electricity,electrochemical methods have emerged as potential approaches for converting and fixing CO_(2).Organic electrochemical synthesis is a promising method for utilizing CO_(2)because it transforms CO_(2)into higher-value chemicals.This review introduces the research aspects of CO_(2)conversion and the mechanisms of CO_(2)organic electrocarboxylation reactions.Recent progress in electrocarboxylation with CO_(2)is discussed,considering organic substrates and cathode types under different reaction mechanisms.Finally,the challenges and prospects in this field are highlighted with the aim of further promoting the fundamental understanding of CO_(2)organic electrocarboxylation.

关 键 词：CO_(2)conversion Organic electrocarboxylation mechanism Carboxylic acids Cathode materials 

分 类 号：O62[理学—有机化学]