废轮胎裂解炭黑在能源存储及转换中的应用进展  

Advances in the Application of Waste Tire Pyrolysis Carbon Black forEnergy Storage and Conversion

作　　者：陈美玲 孙艳芝[1] 吴玉锋[2] 袁浩然[3] 潘军青[1] CHEN Meiling;SUN Yanzhi;WU Yufeng;YUAN Haoran;PAN Junqing(State Key Laboratory of Effective Utilization of Chemical Resources,School of Chemistry,Beijing University of Chemical Technology,Beijing 100029,China;Department of Materials and Manufacturing,Beijing Institute of Technology,Beijing 100124,China;Guangzhou Energy Institute,Chinese Academy of Sciences,Guangzhou 510610,China)

机构地区：[1]北京化工大学化学学院化工资源有效利用国家重点实验室,北京100029 [2]北京工业大学材料与制造学部,北京100124 [3]中国科学院广州能源所,广州510610

出　　处：《材料导报》2024年第8期72-82,共11页Materials Reports

基　　金：国家重点研发计划项目(2019YFC1908304,2023YFC3900040);国家自然科学基金(52070007)。

摘　　要：全球每年大量报废的废轮胎产生引起严重的资源浪费和环境污染等问题,热裂解作为废轮胎高效的最终处理方式之一获得了广泛的应用。裂解炭黑作为废轮胎裂解主要副产物,它的高值化利用有利于推动废轮胎裂解行业健康发展和价值链提升。该裂解炭黑含有高达75%~81%的无定形碳,经过纯化(除灰分)和改性处理可获得具有与商品炭黑导电性相当的多孔碳材料,在能源存储和能源转换方面有着日益重要的应用。本文结合废轮胎裂解炭黑纯化方法以及改性方式,主要围绕裂解炭黑在超级电容器、二次电池和电催化等方面的研究进展,对裂解炭黑资源化研究和应用现状等进行综述分析。With the rapid development of vehicles, plenty of waste tires are produced globally, resulting in serious resource waste and environmental pollution, etc. The pyrolysis process is considered a high-efficiency method for the final treatment of waste tires and has obtained wide application. As a main by-product of the waste tire pyrolysis process, the high-value recycling and utilization of pyrolytic carbon black(CBp) is conducive to the healthy development of the pyrolysis industry and upgrading in full value chains. The CBp contains 75%—81% amorphous carbon, which can be demineralized and modified to obtain porous carbon materials with enhanced electrical conductivity and other properties comparable to commercial carbon black, demonstrating an important role in energy storage and energy conversion applications. This paper combines the purification method of CBp from waste tires and the modification method, mainly focusing on the research progress of CBp in supercapacitors, se- condary batteries and electrocatalysis, etc., and reviews and analyzes the current situation of CBp resourcefulness research and application.

关 键 词：废轮胎 裂解炭黑 超级电容器 二次电池 电催化 

分 类 号：TQ330.381[化学工程—橡胶工业]