Polymer engineering for electrodes of aqueous zinc ion batteries  

作　　者：Zhi Peng Zemin Feng Xuelian Zhou Siwen Li Xuejing Yin Zekun Zhang Ningning Zhao Zhangxing He Lei Dai Ling Wang Chao Lu 

机构地区：[1]School of Chemical Engineering,North China University of Science and Technology,Tangshan 063210,Hebei,China [2]State Key Laboratory of Chemical Resource Engineering,Beijing University of Chemical Technology,Beijing 100029,China

出　　处：《Journal of Energy Chemistry》2024年第4期345-369,共25页能源化学（英文版）

基　　金：financially supported by the National Natural Science Foundation of China(51872090,51772097,22304055);the Hebei Natural Science Fund for Distinguished Young Scholar(E2019209433);the Youth Talent Program of Hebei Provincial Education Department(BJ2018020);the Natural Science Foundation of Hebei Province(E2020209151,E2022209158,B2022209026,D2023209012);the Central Guiding Local Science and Technology Development Fund Project(236Z4409G);the Science and Technology Project of Hebei Education Department(SLRC2019028);the Science and Technology Planning Project of Tangshan City(22130227H)。

摘　　要：With the increasing demand for scalable and cost-effective electrochemical energy storage,aqueous zinc ion batteries(AZIBs)have a broad application prospect as an inexpensive,efficient,and naturally secure energy storage device.However,the limitations suffered by AZIBs,including volume expansion and active materials dissolution of the cathode,electrochemical corrosion,irreversible side reactions,zinc dendrites of the anode,have seriously decelerated the civilianization process of AZIBs.Currently,polymers have tremendous superiority for application in AZIBs attributed to their exceptional chemical stability,tunable structure,high energy density and outstanding mechanical properties.Considering the expanding applications of AZIBs and the superiority of polymers,this comprehensive paper meticulously reviews the benefits of utilizing polymeric applied to cathodes and anodes,respectively.To begin with,with adjustable structure as an entry point,the correlation between polymer structure and the function of energy storage as well as optimization is deeply investigated in respect to the mechanism.Then,depending on the diversity of properties and structures,the development of polymers in AZIBs is summarized,including conductive polymers,redox polymers as well as carbon composite polymers for cathode and polyvinylidene fluoride-,carbonyl-,amino-,nitrile-based polymers for anode,and a comprehensive evaluation of the shortcomings of these strategies is provided.Finally,an outlook highlights some of the challenges posed by the application of polymers and offers insights into the potential future direction of polymers in AZIBs.It is designed to provide a thorough reference for researchers and developers working on polymer for AZIBs.

关 键 词：Aqueous zinc ion batteries POLYMER Multi-function Anode protection Energy storage 

分 类 号：TQ317[化学工程—高聚物工业] TM912[电气工程—电力电子与电力传动]